C₅₇H₉₃ClO₁₂Si₄

Base Information

Chemical Name:C₅₇H₉₃ClO₁₂Si₄
CAS No.:1332271-38-1
Molecular Formula:C₅₇H₉₃ClO₁₂Si₄
Molecular Weight:1118.15
Hs Code.:

C<sub>57</sub>H<sub>93</sub>ClO<sub>12</sub>Si<sub>4</sub>

Synonyms:C₅₇H₉₃ClO₁₂Si₄

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Chemical Property of C₅₇H₉₃ClO₁₂Si₄

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Technology Process of C₅₇H₉₃ClO₁₂Si₄

There total 29 articles about C₅₇H₉₃ClO₁₂Si₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 1332271-67-6
C₅₁H₇₉ClO₁₂Si₃

: 69739-34-0
t-butyldimethylsiyl triflate

: 1332271-38-1
C₅₇H₉₃ClO₁₂Si₄

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at -78 - 0 ℃; for 3h; Inert atmosphere;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: 1332271-25-6
C₃₇H₅₇ClO₈Si₂

: 1332271-38-1
C₅₇H₉₃ClO₁₂Si₄

Guidance literature:: Multi-step reaction with 15 steps

1.1: potassium hexamethylsilazane / tetrahydrofuran; toluene / 1.17 h / -78 °C / Inert atmosphere

1.2: 0.5 h / -78 °C / Inert atmosphere

2.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

3.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

4.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

5.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

6.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

6.2: Inert atmosphere

7.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

8.1: 2,6-dimethylpyridine / dichloromethane / 2.55 h / -78 - -45 °C / Inert atmosphere

9.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 14 h / 20 °C / Inert atmosphere

10.1: pyridinium p-toluenesulfonate / methanol / 16 h / 35 °C / Inert atmosphere

11.1: 2,6-dimethylpyridine / dichloromethane / 0.37 h / 0 °C / Inert atmosphere

12.1: camphor-10-sulfonic acid / methanol; dichloromethane / 5 h / 0 °C / Inert atmosphere

13.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 0.33 h / 20 °C / Inert atmosphere

14.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 2 h / 0 °C / Inert atmosphere

15.1: 2,6-dimethylpyridine / dichloromethane / 3 h / -78 - 0 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; chromium dichloride; dmap; sodium tetrahydroborate; osmium(VIII) oxide; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; camphor-10-sulfonic acid; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; pyridinium p-toluenesulfonate; potassium hexamethylsilazane; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; water; N,N-dimethyl-formamide; acetone; toluene; tert-butyl alcohol; 4.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094

Reference yield:

: 1332271-26-7
C₃₈H₅₆ClF₃O₁₀SSi₂

: 1332271-38-1
C₅₇H₉₃ClO₁₂Si₄

Guidance literature:: Multi-step reaction with 14 steps

1.1: pyridine; pyridine hydrogenfluoride / tetrahydrofuran / 17 h / 20 °C / Inert atmosphere

2.1: tetrapropylammonium perruthennate; 4-methylmorpholine N-oxide / dichloromethane / 4 h / 20 °C / Inert atmosphere; Molecular sieve

3.1: chromium dichloride; nickel dichloride / N,N-dimethyl-formamide / 1 h / 20 °C / Inert atmosphere

4.1: pyridine; Dess-Martin periodane / dichloromethane / 4.5 h / 20 °C / Inert atmosphere

5.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.5 h / 0 °C / Inert atmosphere

5.2: Inert atmosphere

6.1: tris(dimethylamino)sulfonium trimethylsilyldifluoride / N,N,N,N,N,N-hexamethylphosphoric triamide / 24 h / 70 °C / Inert atmosphere

7.1: 2,6-dimethylpyridine / dichloromethane / 2.55 h / -78 - -45 °C / Inert atmosphere

8.1: osmium(VIII) oxide; water; 4-methylmorpholine N-oxide / acetone; tert-butyl alcohol / 14 h / 20 °C / Inert atmosphere

9.1: pyridinium p-toluenesulfonate / methanol / 16 h / 35 °C / Inert atmosphere

10.1: 2,6-dimethylpyridine / dichloromethane / 0.37 h / 0 °C / Inert atmosphere

11.1: camphor-10-sulfonic acid / methanol; dichloromethane / 5 h / 0 °C / Inert atmosphere

12.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 0.33 h / 20 °C / Inert atmosphere

13.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane; water / 2 h / 0 °C / Inert atmosphere

14.1: 2,6-dimethylpyridine / dichloromethane / 3 h / -78 - 0 °C / Inert atmosphere

With pyridine; 2,6-dimethylpyridine; chromium dichloride; dmap; sodium tetrahydroborate; osmium(VIII) oxide; tetrapropylammonium perruthennate; cerium(III) chloride heptahydrate; camphor-10-sulfonic acid; tris(dimethylamino)sulfonium trimethylsilyldifluoride; water; pyridinium p-toluenesulfonate; Dess-Martin periodane; pyridine hydrogenfluoride; 4-methylmorpholine N-oxide; dicyclohexyl-carbodiimide; 2,3-dicyano-5,6-dichloro-p-benzoquinone; nickel dichloride; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; dichloromethane; water; N,N-dimethyl-formamide; acetone; tert-butyl alcohol; 3.1: Nozaki-Hiyama-Kishi reaction;
DOI:10.1016/j.tet.2011.04.094