cis,cis-3,5-diazidocyclohexyl benzoate

Base Information

Chemical Name:cis,cis-3,5-diazidocyclohexyl benzoate
CAS No.:674782-60-6
Molecular Formula:C₁₃H₁₄N₆O₂
Molecular Weight:286.293
Hs Code.:

Synonyms:cis,cis-3,5-diazidocyclohexyl benzoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of cis,cis-3,5-diazidocyclohexyl benzoate

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Technology Process of cis,cis-3,5-diazidocyclohexyl benzoate

There total 3 articles about cis,cis-3,5-diazidocyclohexyl benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 65-85-0,8013-63-6
benzoic acid

: 675616-60-1
cis-3,5-diazido-trans-hydroxycyclohexane

: 674782-60-6
cis,cis-3,5-diazidocyclohexyl benzoate

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; at -50 - 20 ℃; for 3h; Inert atmosphere;
DOI:10.1039/c9dt00773c

Reference yield:

: 50409-12-6,13314-30-2
cis,cis-1,3,5-trihydroxycyclohexane

: 674782-60-6
cis,cis-3,5-diazidocyclohexyl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: pyridine; MsCl / 0 - 20 °C

1.2: 62 percent / NaN₃ / dimethylformamide / 70 °C

2.1: 46 percent / Ph₃P; DEAD / tetrahydrofuran / -50 - 20 °C

With pyridine; methanesulfonyl chloride; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; 2.1: Mitsunobu reaction;
DOI:10.1021/jo035290r

Reference yield:

: 61121-93-5
cis-1,3-ditosyloxy-5-hydroxycyclohexane

: 674782-60-6
cis,cis-3,5-diazidocyclohexyl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: sodium azide / N,N-dimethyl-formamide / 24 h / 70 °C

2: triphenylphosphine; diethylazodicarboxylate / tetrahydrofuran / 3 h / -50 - 20 °C / Inert atmosphere

With sodium azide; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; N,N-dimethyl-formamide; 1: |Mitsunobu Displacement;
DOI:10.1039/c9dt00773c