(1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol

Base Information

Chemical Name:(1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol
CAS No.:79918-68-6
Molecular Formula:C₃₂H₃₈O₂
Molecular Weight:454.653
Hs Code.:

Synonyms:(1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol

Suppliers and Price of (1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol

There total 1 articles about (1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 76-83-5
trityl chloride

: 185997-26-6
(1R,3aR,7aR)-1-((S)-1-hydroxypropan-2-yl)-7a-methyloctahydro-1H-inden-4-ol

: 79918-68-6
(1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol

Guidance literature:: With pyridine; at 100 ℃; for 36h;
DOI:10.1021/jo00341a031

Reference yield: 97.0%

: 79918-68-6
(1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol

: 79918-69-7
(1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-one

Guidance literature:: With Collins oxidation agent; In dichloromethane; for 0.333333h;
DOI:10.1021/jo00341a031

Reference yield:

: 79918-68-6
(1R,3aR,7aR)-7a-Methyl-1-((S)-1-methyl-2-trityloxy-ethyl)-octahydro-inden-4-ol

: 79918-72-2
C₂₀H₃₀N₂O₃S

Guidance literature:: Multi-step reaction with 3 steps

1: 97 percent / Collins reagent (CrO₃*2Py) / CH₂Cl₂ / 0.33 h

2: 1.) 60percent aq. AcOH, 2.) KOH / 1.) 100 deg C, 1.5 h, 2.) methanol, reflux, 2 h

3: 85 percent / ethanol / Ambient temperature

With potassium hydroxide; Collins oxidation agent; acetic acid; In ethanol; dichloromethane;
DOI:10.1021/jo00341a031