[3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester

Base Information

• Chemical Name: [3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester
• CAS No.: 930120-78-8
• Molecular Formula: C₄₇H₅₇N₅O₂
• Molecular Weight: 724.002
• Mol file: 930120-78-8.mol

Synonyms:[3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester

Chemical Property of [3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester

There total 3 articles about [3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

pyrrole (109-97-7,30604-81-0) + 3-acetylphenylcarbamic acid benzyl ester (42865-67-8) + pentan-3-one (96-22-0) → [3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester (930120-78-8)

Guidance literature:

With boron trifluoride diethyl etherate; In methanol; dichloromethane; at 20 ℃; for 48h;

DOI:10.1021/ja001308t

Reference yield:

1-(3-aminophenyl)ethanone (99-03-6) → [3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester (930120-78-8)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / CH₂Cl₂ / 20 °C

2: 23 percent / borontrifluoride-etherate / methanol; CH₂Cl₂ / 48 h / 20 °C

With pyridine; boron trifluoride diethyl etherate; In methanol; dichloromethane;

DOI:10.1021/ja001308t

Reference yield:

benzyl chloroformate (501-53-1,94274-21-2) → [3-(10,10,15,15,20,20-hexaethyl-5-methyl-porphyrinogen-5-yl)-phenyl]-carbamic acid benzyl ester (930120-78-8)

Guidance literature:

Multi-step reaction with 2 steps

1: pyridine / CH₂Cl₂ / 20 °C

2: 23 percent / borontrifluoride-etherate / methanol; CH₂Cl₂ / 48 h / 20 °C

With pyridine; boron trifluoride diethyl etherate; In methanol; dichloromethane;

DOI:10.1021/ja001308t

upstream raw materials:

pyrrole

3-acetylphenylcarbamic acid benzyl ester

pentan-3-one

1-(3-aminophenyl)ethanone

Downstream raw materials:

meso-heptaethylcalix[4]pyrrole-meso-3-aminophenyl