5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester

Base Information

Chemical Name:5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester
CAS No.:405159-96-8
Molecular Formula:C₂₅H₃₄O₄Si
Molecular Weight:426.628
Hs Code.:

Synonyms:5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester

Suppliers and Price of 5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester

There total 2 articles about 5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 84752-35-2
5-hydroxy-2,2-dimethyl-3-oxo-pentanoic ethyl ester

: 58479-61-1
tert-butylchlorodiphenylsilane

: 405159-96-8
5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide;
DOI:10.1039/b101669p

Reference yield:

: 600-00-0
ethyl 2-bromoisobutyrate

: 405159-96-8
5-(tert-butyldiphenylsilanyloxy)-3-oxo-2,2-dimethyl-pentanoic ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 71 percent / Zn / tetrahydrofuran / 3 h

2: 90 percent / imidazole / dimethylformamide / 14 h / 20 °C

With 1H-imidazole; zinc; In tetrahydrofuran; N,N-dimethyl-formamide; 1: Reformatsky reaction;
DOI:10.1002/1521-3765(20011217)7:24<5299::AID-CHEM5299>3.0.CO;2-X