trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)

Base Information

Chemical Name:trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)
CAS No.:129873-68-3
Molecular Formula:C₅₁H₄₁ClN₃P₂Ru*ClO₄
Molecular Weight:993.828
Hs Code.:

trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO<sub>4</sub>)

Synonyms:trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)

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Chemical Property of trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)

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Technology Process of trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)

There total 2 articles about trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1100716-05-9,72905-34-1,72937-76-9
cis-{Ru(Cl)2(triphenylphosphine)(2,2':6',2''-terpyridine)}

: 129873-68-3
trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)

Guidance literature:: With P(C₆H₅)3; In ethanol; acetone; under inert atmosphere, 2:1 acetone/ethanol, stirred at room temp. for 3 h; complete removal of solvent, dissolved in H2O, pptd. by addn. of a soln. of NaClO4, vac. filtration, washed with H2O and Et2O;

Reference yield: 76.0%

: 72905-30-7
(2,2':6',2''-terpyridine)trichlororuthenium(III)

: 129873-68-3
trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)

Guidance literature:: With Zn(Hg); P(C₆H₅)3; In dichloromethane; Irradiation (UV/VIS); under inert atmosphere, 3.5 equiv. phosphine, heated at reflux for 1 day, irrdn. with a 120-W tungsten light for 12 h; cooled, filtered, complete removal of solvent, dissolved in 3:1 EtOH/H2O, addn. of an aq. soln. of NaClO4, EtOH removed by evapn., vac. filtration, washed (H2O and Et2O), eluted through an alumina column with acetone, volume reduced, triturated in Et2O;

Reference yield: 47.0%

: 129873-68-3
trans-{Ru(Cl)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)

: sodium perchlorate

: trans-{Ru(nitro)(triphenylphosphine)2(2,2':6',2''-terpyridine)}(ClO₄)

Guidance literature:: With NaNO₂; In ethanol; water; under N2, soln. of Ru-compd. and NaNO2 in 1:1 ethanol/H2O refluxed for 3 h, allowed to cool, addn. of excess NaClO4 in H2O; volume reduced, vac. filtration (first fraction), addn. of NaClO4 to the filtrate, chilled to ice temp. (second fraction);