Bicyclo(3.3.0)octa-2,6-diene

Base Information

Chemical Name:Bicyclo(3.3.0)octa-2,6-diene
CAS No.:41527-66-6
Molecular Formula:C₈H₁₀
Molecular Weight:106.167
Hs Code.:
DSSTox Substance ID:DTXSID50961798
Nikkaji Number:J1.383.748A
Mol file:41527-66-6.mol

Synonyms:1,3a,4,6a-tetrahydropentalene;Bicyclo(3.3.0)octa-2,6-diene;Bicyclo[3.3.0]octa-2,6-diene;41527-66-6;DTXSID50961798;AKOS024436819

Suppliers and Price of Bicyclo(3.3.0)octa-2,6-diene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of Bicyclo(3.3.0)octa-2,6-diene

Chemical Property:

Vapor Pressure:3.47mmHg at 25°C
Boiling Point:158°C at 760 mmHg
Flash Point:27.2°C
Density:0.969g/cm³
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:0
Exact Mass:106.078250319
Heavy Atom Count:8
Complexity:124

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1C=CC2C1C=CC2

Technology Process of Bicyclo(3.3.0)octa-2,6-diene

There total 2 articles about Bicyclo(3.3.0)octa-2,6-diene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 29185-91-9
tetracyclo<3.3.0^2,4.0^3,6>octane

: 100-42-5,25038-60-2,25247-68-1,28213-80-1,28325-75-9,79637-11-9,9003-53-6
styrene

: 100-41-4,27536-89-6
ethylbenzene

: 41164-14-1
cis-bicyclo<3.3.0>octa-2,7-diene

: 17618-97-2,41527-66-6,104393-61-5,110269-92-6
cis-Bicyclo<3.3.0>octa-2,6-diene

: 108-88-3,15644-74-3,16713-13-6
toluene

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

Guidance literature:: at 560 ℃; for 2h; under 2 Torr; Product distribution; the effect of temperature was investigated;
DOI:10.1016/0040-4020(82)85168-5

Reference yield:

: 29185-91-9
tetracyclo<3.3.0^2,4.0^3,6>octane

: 41164-14-1
cis-bicyclo<3.3.0>octa-2,7-diene

: 1192-86-5
1-ethenyl-1,3-cyclohexadiene

: 17618-97-2,41527-66-6,104393-61-5,110269-92-6
cis-Bicyclo<3.3.0>octa-2,6-diene

: 71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1
benzene

Guidance literature:: at 473 ℃; for 0.000555556h; under 2 Torr; Further byproducts given;
DOI:10.1016/0040-4020(82)85168-5

Reference yield:

: 17618-97-2,41527-66-6,104393-61-5,110269-92-6
cis-Bicyclo<3.3.0>octa-2,6-diene

: 104393-72-8
Toluene-4-sulfonic acid (S)-2-hydroxy-2-(1S,3aS,6aS)-1,3a,6,6a-tetrahydro-pentalen-1-yl-ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 1.25 eq. SnCl₄ / 3.5 h / -78 °C

2: 83 percent / LiAlH₄ / tetrahydrofuran

3: pyridine / CH₂Cl₂ / 18 h / from -79 to -33 deg C

With pyridine; lithium aluminium tetrahydride; tin(IV) chloride; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja00281a057