(phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane

Base Information

Chemical Name:(phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane
CAS No.:137928-14-4
Molecular Formula:C₂₂H₁₁ClCo₂O₆Si
Molecular Weight:552.851
Hs Code.:

Synonyms:(phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane

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Technology Process of (phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane

There total 1 articles about (phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 136910-07-1
HClSi(CC-Ph)2

: 137928-14-4
(phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane

Guidance literature:: In toluene; under N2, a soln. of Co2(CO)8 is added dropwise to a soln. of the ligand (equimolar amt.) in petroleum ether/toluene at 25°C, stirred for 4 h; volatile compds. are removed in high vac., residue is filtered (silica gel), solvent is removed; elem. anal.;
DOI:10.1016/0022-328X(91)80197-R

Reference yield: 88.0%

: 15226-74-1,61091-28-9,61117-58-6
dicobalt octacarbonyl

: 137928-14-4
(phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane

: 137988-57-9
bis{(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane

Guidance literature:: In toluene; under N2, a soln. of Co2(CO)8 is added dropwise to a soln. of the cobalt-silane complex (equimolar amt.) in petroleum ether/toluene at 25°C, stirred for 4 h; volatile compds. are removed in high vac., residue is filtered (silica gel), recrystn. at -30°C (petroleum ether/toluene) ; elem. anal.;
DOI:10.1016/0022-328X(91)80197-R

Reference yield: 85.0%

: 137928-14-4
(phenylethynyl){(η2-phenylethynyl)dicobalthexacarbonyl}chlorosilane

: 138033-47-3
{{(η(2)-CCC6H5)Co2(CO)6}{C6H5CCSi(H)(OH)}

Guidance literature:: With water; In tetrahydrofuran; byproducts: HCl; to ((η(2)-CCPh)Co2(CO)6)((PhCC)Si(H)(Cl)) in THF water added, stirred 4 h at 25°C; the volatile components evapd. by high vac., filtered with CH2Cl2/petroleum ether through silica gel; volatiles removed, crystn. from toluene/n-pentane at -30°C; elem. anal.;
DOI:10.1016/0022-328X(91)86348-T