allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside

Base Information

Chemical Name:allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside
CAS No.:1621135-56-5
Molecular Formula:C₂₅H₃₂O₆
Molecular Weight:428.525
Hs Code.:

Synonyms:allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside

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Technology Process of allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside

There total 2 articles about allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 1621135-55-4
allyl 3,6-dideoxy-β-D-ribohexofuranoside

: 824-94-2
p-methoxybenzyl chloride

: 1621135-56-5
allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside

Guidance literature:: allyl 3,6-dideoxy-β-D-ribohexofuranoside; With sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil; for 0.0833333h; Cooling with ice; Inert atmosphere;

p-methoxybenzyl chloride; In tetrahydrofuran; N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 3h; Inert atmosphere;
DOI:10.1002/asia.201301647

Reference yield:

: 58475-17-5
(R)-1-((3aR,5S,6aR)-2,2-dimethyltetrahydrofuro[2,3-d][1,3]dioxol-5-yl)ethan-1-ol

: 1621135-56-5
allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside

Guidance literature:: Multi-step reaction with 4 steps

1.1: triethylamine; dmap / dichloromethane / 5 h / 0 - 20 °C / Inert atmosphere

2.1: toluene-4-sulfonic acid / tetrahydrofuran / 4 h / Reflux; Inert atmosphere

3.1: lithium aluminium tetrahydride / tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere

4.1: sodium hydride / tetrahydrofuran; mineral oil; N,N-dimethyl-formamide / 0.08 h / Cooling with ice; Inert atmosphere

4.2: 3 h / 20 °C / Inert atmosphere

With dmap; lithium aluminium tetrahydride; sodium hydride; toluene-4-sulfonic acid; triethylamine; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1002/asia.201301647

Reference yield:

: 1621135-56-5
allyl 3,6-dideoxy-2,5-di-O-(p-methoxybenzyl)-β-D-ribohexofuranoside

: C₂₂H₂₈O₆

Guidance literature:: With tetrakis(triphenylphosphine) palladium⁽⁰⁾; 1,3-dimethylbarbituric acid; triphenylphosphine; In ethanol; at 20 ℃; for 6h; Inert atmosphere;
DOI:10.1002/asia.201301647