(1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene

Base Information

Chemical Name:(1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene
CAS No.:147728-73-2
Molecular Formula:C₂₅H₃₀O₂
Molecular Weight:362.512
Hs Code.:

Synonyms:(1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene

Suppliers and Price of (1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene

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Chemical Property of (1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene

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Technology Process of (1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene

There total 8 articles about (1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 155192-06-6
(1R, 5S, 9R)-9-formyl-5-methylbicyclo<3.3.1>-6-nonen-2-one

: 147728-73-2
(1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / liquid ammonia, lithium / tetrahydrofuran; ethanol / 1 h / -34 °C

2: 99 percent / 50percent sodium hydride in mineral oil / dimethylformamide / 8 h / 0 - 22 °C

With ammonia; lithium; sodium hydride; In tetrahydrofuran; ethanol; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(01)80785-7

Reference yield:

: (1R, 4R, 8R, 9R, 10S)-4-methyl-2-oxatricyclo<6.4.0.0^4,9>-5-dodecen-1,10-diol

: 147728-73-2
(1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / sodium periodate / acetonitrile; H₂O / 2 h / 0 - 25 °C

2: 93 percent / liquid ammonia, lithium / tetrahydrofuran; ethanol / 1 h / -34 °C

3: 99 percent / 50percent sodium hydride in mineral oil / dimethylformamide / 8 h / 0 - 22 °C

With sodium periodate; ammonia; lithium; sodium hydride; In tetrahydrofuran; ethanol; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4020(01)80785-7

Reference yield:

: (1R,2R,5R,7S,9R)-9-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-methoxymethoxy-5-methyl-tricyclo[3.3.1.0^2,7]nonan-6-ol

: 147728-73-2
(1R, 2S, 5S, 9R)-2-benzyloxy-9-benzyloxymethyl-5-methylbicyclo<3.3.1>-6-nonene

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / pyridine, N,N-dimethylaminopyridine / 12 h / 0 °C

2: 91 percent / 2N HCl / acetonitrile / 24 h / 25 °C

3: 99 percent / sodium periodate / acetonitrile; H₂O / 2 h / 0 - 25 °C

4: 93 percent / liquid ammonia, lithium / tetrahydrofuran; ethanol / 1 h / -34 °C

5: 99 percent / 50percent sodium hydride in mineral oil / dimethylformamide / 8 h / 0 - 22 °C

With pyridine; hydrogenchloride; dmap; sodium periodate; ammonia; lithium; sodium hydride; In tetrahydrofuran; ethanol; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1016/S0040-4020(01)80785-7