tricyclo<3.2.1.0^2,7>oct-3-ene

Base Information

• Chemical Name: tricyclo<3.2.1.0^2,7>oct-3-ene
• CAS No.: 3725-23-3
• Molecular Formula: C₈H₁₀
• Molecular Weight: 106.167
• Mol file: 3725-23-3.mol

Synonyms:tricyclo<3.2.1.0^2,7>oct-3-ene

Chemical Property of tricyclo<3.2.1.0^2,7>oct-3-ene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tricyclo<3.2.1.0^2,7>oct-3-ene

There total 8 articles about tricyclo<3.2.1.0^2,7>oct-3-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

7-methylenebicyclo<4.1.0>hept-2-ene (36398-96-6) → ethylbenzene (100-41-4,27536-89-6) + tricyclo<3.2.1.02,7>oct-3-ene (3725-23-3) + 7-methylene bicyclo<4.1.01,6>hept-3-ene (51422-66-3)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; Product distribution; Mechanism;

Reference yield: 44.0%

bicyclo<3.2.1>octa-3,6-dien-2-one tosylhydrazone lithium salt (80976-42-7) → tetracyclo<3.3.02,8.04,6.0>octane (765-72-0) + bicyclo<3.2.1>octa-2,6-diene (4096-95-1,61617-42-3) + 5-ethynyl-1,3-cyclohexadiene (57015-38-0) + tricyclo<3.2.1.02,7>oct-3-ene (3725-23-3)

Guidance literature:

at 198 ℃; for 0.166667h; under 0.1 Torr; Yield given. Further byproducts given;

DOI:10.1021/jo00132a011

Reference yield: 25.0%

3-Vinyl-1,4-cyclohexadien (85633-68-7) → 2-ethenyl-1,3-cyclohexadiene (62939-61-1) + 1-ethenyl-1,3-cyclohexadiene (1192-86-5) + tricyclo<3.2.1.02,7>oct-3-ene (3725-23-3)

Guidance literature:

In tetrachloromethane; at 400 ℃; under 0.008 Torr;

upstream raw materials:

(1Z,3Z,5Z)-Cycloocta-1,3,5-triene

cis-1-cycloocten-3-yne

7-methylenebicyclo<4.1.0>hept-2-ene

bicyclo<3.2.1>octa-3,6-dien-2-one tosylhydrazone

Downstream raw materials:

bicyclo<3.2.1>octane

Refernces

• 1、 Brinker, Udo H.,Koenig, Lothar. "Carbene Rearrangements, XI. Bicyclooct-2-en-7-ylidene". . p. 894 - 910. Retrieved 2007/10/02.
• 2、 Freeman, Peter K.,Swenson, Karl E.. "Chemistry of 2-Carbenabicyclooctadiene". . p. 2033 - 2039. Retrieved 2007/10/02.