S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate

Base Information

Chemical Name:S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate
CAS No.:1395062-13-1
Molecular Formula:CF₃O₃S*C₁₇H₁₈BrF₂S
Molecular Weight:521.367
Hs Code.:

Synonyms:S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate

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Chemical Property of S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate

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Technology Process of S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate

There total 3 articles about S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 488-23-3
1,2,3,4-Tetramethylbenzene

: ((bromodifluoromethyl)sulfinyl)benzene

: 1395062-13-1
S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate

Guidance literature:: With sodium tetrahydroborate; In dichloromethane; at 0 - 20 ℃; for 12h; Inert atmosphere;
DOI:10.1039/c2nj40255f

Reference yield:

: 78031-08-0
[(bromodifluoromethyl)sulfanyl]benzene

: 1395062-13-1
S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate

Guidance literature:: Multi-step reaction with 2 steps

1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 20 °C

2: sodium tetrahydroborate / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere

With sodium tetrahydroborate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1039/c2nj40255f

Reference yield:

: 108-98-5
thiophenol

: 1395062-13-1
S-bromodifluoromethyl-S-phenyl-2,3,4,5-tetramethylphenylsulfonium triflate

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0 °C / Inert atmosphere

1.2: -15 - 20 °C / Inert atmosphere

2.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0 - 20 °C

3.1: sodium tetrahydroborate / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere

With sodium tetrahydroborate; sodium hydride; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1039/c2nj40255f