3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose

Base Information

Chemical Name:3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose
CAS No.:99050-17-6
Molecular Formula:C₁₇H₂₃IO₄
Molecular Weight:418.272
Hs Code.:

Synonyms:3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose

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Chemical Property of 3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose

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Technology Process of 3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose

There total 5 articles about 3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 55533-90-9,99050-13-2
3-O-Benzyl-6-desoxy-1,2-O-isopropyliden-3-C-methyl-β-L-talo-hexofuranose

: 99050-17-6
3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose

Guidance literature:: With 1H-imidazole; iodine; triphenylphosphine; In toluene; for 1.5h; Heating;

Reference yield:

: 55533-86-3,120615-67-0
3-O-Benzyl-3-C-methyl-1,2-O-isopropylidene-α-D-allofuranose

: 99050-17-6
3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose

Guidance literature:: Multi-step reaction with 5 steps

1: 82 percent / pyridine / -20 °C

2: pyridine / 20 h / Ambient temperature

3: K₂CO₃ / methanol / 5 h / Ambient temperature

4: 91 percent / LiAlH₄ / diethyl ether / 1 h / Ambient temperature

5: 83 percent / PPh₃/imidazole/iodine / toluene / 1.5 h / Heating

With 1H-imidazole; lithium aluminium tetrahydride; iodine; potassium carbonate; triphenylphosphine; In pyridine; methanol; diethyl ether; toluene;

Reference yield:

: 55533-89-6
5,6-Anhydro-3-O-benzyl-1,2-O-isopropyliden-3-C-methyl-β-L-talo-hexofuranose

: 99050-17-6
3-O-Benzyl-5,6-didesoxy-1,2-O-isopropyliden-5-iod-3-C-methyl-α-D-allo-hexofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: 91 percent / LiAlH₄ / diethyl ether / 1 h / Ambient temperature

2: 83 percent / PPh₃/imidazole/iodine / toluene / 1.5 h / Heating

With 1H-imidazole; lithium aluminium tetrahydride; iodine; triphenylphosphine; In diethyl ether; toluene;