(S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline

Base Information

Chemical Name:(S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline
CAS No.:1309366-77-5
Molecular Formula:C₂₃H₄₃NOSi
Molecular Weight:377.686
Hs Code.:

Synonyms:(S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline

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Chemical Property of (S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline

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Technology Process of (S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline

There total 5 articles about (S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 1309366-63-9
N-(2-chlorohexyl)-N,3-dimethylaniline

: 1024955-85-8
{3-[9-borabicyclo[3.3.1]non-9-yl]propoxy}(tert-butyl)dimethylsilane

: 1309366-77-5
(S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline

Guidance literature:: With nickel(II) bromide 2-methoxyethyl ether complex; (1R,2R)-N,N’-dimethyl-1,2-di(naphthalen-1-yl)ethane-1,2-diamine; potassium tert-butylate; In di-isopropyl ether; hexan-1-ol; at 20 ℃; for 40h; optical yield given as %ee; enantioselective reaction;
DOI:10.1021/ja203560q

Reference yield:

: 1309366-99-1
C₁₄H₂₀ClNO

: 1309366-77-5
(S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline

Guidance literature:: Multi-step reaction with 2 steps

1: borane-THF / tetrahydrofuran / 18 h / Reflux

2: nickel(II) bromide 2-methoxyethyl ether complex; (1R,2R)-N,N’-dimethyl-1,2-di(naphthalen-1-yl)ethane-1,2-diamine; potassium tert-butylate / di-isopropyl ether; hexan-1-ol / 40 h / 20 °C

With borane-THF; nickel(II) bromide 2-methoxyethyl ether complex; (1R,2R)-N,N’-dimethyl-1,2-di(naphthalen-1-yl)ethane-1,2-diamine; potassium tert-butylate; In tetrahydrofuran; di-isopropyl ether; hexan-1-ol; 2: Suzuki cross coupling;
DOI:10.1021/ja203560q

Reference yield:

: 85807-85-8
Allyloxy-tert-butyl-dimethyl-silane

: 1309366-77-5
(S)-N-(2-(3-(tert-butyldimethylsilyloxy)propyl)hexyl)-N,3-dimethylaniline

Guidance literature:: Multi-step reaction with 2 steps

1: di-isopropyl ether / 1 h / 60 °C

2: nickel(II) bromide diethylene glycol dimethyl ether; (1R,2R)-N,N’-dimethyl-1,2-di(naphthalen-1-yl)ethane-1,2-diamine; potassium tert-butylate / di-isopropyl ether; hexan-1-ol / 40 h / 20 °C

With nickel(II) bromide diethylene glycol dimethyl ether; (1R,2R)-N,N’-dimethyl-1,2-di(naphthalen-1-yl)ethane-1,2-diamine; potassium tert-butylate; In di-isopropyl ether; hexan-1-ol; 2: Suzuki cross coupling;
DOI:10.1021/ja203560q