methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5

Base Information

Chemical Name:methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5
CAS No.:205987-04-8
Molecular Formula:C₅₅H₆₀O₁₁
Molecular Weight:897.075
Hs Code.:

Synonyms:methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5

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Chemical Property of methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5

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Technology Process of methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5

There total 21 articles about methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 53008-65-4,641635-63-4
methyl 2,3,4-tri-O-benzyl-D-glucopyranoside

: 74372-90-0
3,4,6-tri-O-benzyl-D-glucal epoxide

: 205987-04-8
methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5

Guidance literature:: With bis(4-fluorophenyl)(hydroxy)borane; In tetrahydrofuran; at -80 ℃; for 6h; stereoselective reaction; Inert atmosphere;
DOI:10.1021/acs.orglett.6b02488

Reference yield: 92.0%

: 20672-66-6,40246-26-2,84926-76-1,114179-79-2,115184-49-1
3,4,6-tri-O-benzyl-D-glucopyranose

: 76679-47-5
methyl-2,3,4-tri-O-benzyl-6-O-trifluoromethanesulfonyl-α-D-glucopyranoside

: 205987-04-8
methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5

Guidance literature:: 3,4,6-tri-O-benzyl-D-glucopyranose; With bis(acetylacetonate)nickel(II); In 1,2-dichloro-ethane; toluene; at 20 ℃; for 0.166667h; Molecular sieve; Inert atmosphere;

With N-ethyl-N,N-diisopropylamine; In 1,2-dichloro-ethane; toluene; for 0.166667h; Molecular sieve; Inert atmosphere;

methyl-2,3,4-tri-O-benzyl-6-O-trifluoromethanesulfonyl-α-D-glucopyranoside; In 1,2-dichloro-ethane; toluene; at 20 ℃; for 36h; Molecular sieve; Inert atmosphere;

Reference yield: 85.0%

: 2-O-(methyl-2,3,4-tri-O-benzyl-6-O-dimethylsilyl-α-D-glucopyranosyl)-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride

: 205987-04-8
methyl 3,4,6-tri-O-benzyl-α-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-α-D-glucopyranoside S5

Guidance literature:: 2-O-(methyl-2,3,4-tri-O-benzyl-6-O-dimethylsilyl-α-D-glucopyranosyl)-3,4,6-tri-O-benzyl-β-D-glucopyranosyl fluoride; With tris(pentafluorophenyl)borate; In toluene; at 23 ℃; for 1h; Inert atmosphere;

With tetrabutyl ammonium fluoride; In tetrahydrofuran; toluene; at 23 ℃; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/jacs.0c03165