methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside

Base Information

Chemical Name:methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside
CAS No.:1392067-12-7
Molecular Formula:C₂₁H₃₀O₈
Molecular Weight:410.464
Hs Code.:

Synonyms:methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside

Suppliers and Price of methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside

There total 4 articles about methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1252047-54-3
(2'S,3'S)-methyl 6-deoxy-2-O-(4-methoxybenzyl)-3,4-O-(2',3'-dimethoxybutane-2',3'-diyl)-6-iodo-α-D-mannopyranoside

: 1392067-12-7
methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere;
DOI:10.1021/jo301240j

Reference yield:

: 197577-12-1
methyl 6-deoxy-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-6-iodo-α-D-mannoside

: 1392067-12-7
methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: (1S)-(+)-camphorsulfonic acid monohydrate / dichloromethane / 16 h / 20 °C

2: potassium tert-butylate / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

With (1S)-(+)-camphorsulfonic acid monohydrate; potassium tert-butylate; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo301240j

Reference yield:

: 176897-12-4
(2S,3S,4aR,5R,7S,8S,8aR)-5-(hydroxymethyl)-2,3,7-trimethoxy-2,3-dimethylhexahydro-2Hpyrano[3,4-b][1,4]dioxin-8-ol4

: 1392067-12-7
methyl 6-deoxy-2-O-(p-methoxy)benzyl-3,4-O-(2,3-dimethoxybutane-2,3-diyl)-α-D-lyxo-hex-5-enopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: triphenylphosphine; 1H-imidazole; iodine / tetrahydrofuran / Reflux

2: (1S)-(+)-camphorsulfonic acid monohydrate / dichloromethane / 16 h / 20 °C

3: potassium tert-butylate / tetrahydrofuran / 1 h / 20 °C / Inert atmosphere

With 1H-imidazole; (1S)-(+)-camphorsulfonic acid monohydrate; potassium tert-butylate; iodine; triphenylphosphine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo301240j