Technology Process of C15H22O5
There total 5 articles about C15H22O5 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate;
4A MS;
In
dichloromethane;
at -30 ℃;
for 12h;
Title compound not separated from byproducts.;
DOI:10.1016/j.tetlet.2007.04.136
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 73 percent / DIBALH / CH2Cl2 / 0.67 h / -78 °C
2: (+)-diisopropyl tartrate; Ti(OiPr)4; TBHP / 4A MS / CH2Cl2 / 12 h / -30 °C
With
titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; diisobutylaluminium hydride;
4A MS;
In
dichloromethane;
2: Katsuki-Sharpless asymmetric epoxidation;
DOI:10.1016/j.tetlet.2007.04.136
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: OsO4; NMO / dioxane / 1 h / 23 °C / pH 7
1.2: 68 percent / NaIO4 / dioxane / 3 h
2.1: 99 percent / NaH / tetrahydrofuran / 12.5 h / 23 °C
3.1: 73 percent / DIBALH / CH2Cl2 / 0.67 h / -78 °C
4.1: (+)-diisopropyl tartrate; Ti(OiPr)4; TBHP / 4A MS / CH2Cl2 / 12 h / -30 °C
With
titanium(IV) isopropylate; tert.-butylhydroperoxide; osmium(VIII) oxide; N-methyl-2-indolinone; L-(+)-diisopropyl tartrate; sodium hydride; diisobutylaluminium hydride;
4A MS;
In
tetrahydrofuran; 1,4-dioxane; dichloromethane;
2.1: Horner-Wadsworth-Emmons reaction / 4.1: Katsuki-Sharpless asymmetric epoxidation;
DOI:10.1016/j.tetlet.2007.04.136
