(triphos)Ir(η4-benzene)(BPh4)

Base Information

Chemical Name:(triphos)Ir(η4-benzene)(BPh4)
CAS No.:135006-00-7
Molecular Formula:C₂₄H₂₀B*C₄₇H₄₅IrP₃
Molecular Weight:1214.25
Hs Code.:

Synonyms:(triphos)Ir(η4-benzene)(BPh4)

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Chemical Property of (triphos)Ir(η4-benzene)(BPh4)

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Technology Process of (triphos)Ir(η4-benzene)(BPh4)

There total 5 articles about (triphos)Ir(η4-benzene)(BPh4) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 134882-90-9
(CH₃C(CH₂P(C₆H₅)2)3)Ir(C₂H₄)2⁽¹⁺⁾*B(C₆H₅)4^(1-) = {(CH₃C(CH₂P(C₆H₅)2)3)Ir(C₂H₄)2}{B(C₆H₅)4}

: 74-86-2,25067-58-7
acetylene

: 135006-00-7
(triphos)Ir(η4-benzene)(BPh4)

Guidance literature:: In tetrahydrofuran; dissolving Ir-complex under ethyne (1 atm) at room temperature, replacing ethyne with nitrogen after 1 h; addn. of ethanol, partial evapn. of solvent, filtn., washing (n-pentane), elem. anal.;
DOI:10.1021/om00017a067

Reference yield: 80.0%

: 154798-32-0
(CH₃C(CH₂P(C₆H₅)2)3)Ir((CH)4)(Cl)

: 143-66-8
sodium tetraphenyl borate

: 74-86-2,25067-58-7
acetylene

: 135006-00-7
(triphos)Ir(η4-benzene)(BPh4)

Guidance literature:: With TlPF₆; In tetrahydrofuran; ethanol; byproducts: TlCl; addn. of Ir-complex to a stirred soln. of TlPF6 in THF under a steady stream of ethyne at room temperature, filtn., addn. of NaBPh4 in ethanol; partial evapn. of solvent under a strem of nitrogen;
DOI:10.1021/om00017a067

Reference yield: 65.0%

: 128549-59-7
{(triphos)IrCl(C₂H₄)}

: 143-66-8
sodium tetraphenyl borate

: 74-86-2,25067-58-7
acetylene

: 135006-00-7
(triphos)Ir(η4-benzene)(BPh4)

Guidance literature:: With TlPF₆; In tetrahydrofuran; byproducts: TlCl; stirring under ethyne (1 atm) at room temperature for 2 h, replacing ethyne with nitrogen; filtn., addn. of NaBPH4 and n-heptane, recrystn. (THF/ethanol/n-heptane);
DOI:10.1021/om00017a067