Diethyl allyl-2-cyclopenten-1-ylmalonate

Base Information

• Chemical Name: Diethyl allyl-2-cyclopenten-1-ylmalonate
• CAS No.: 93981-13-6
• Molecular Formula: C15H22 O4
• Molecular Weight: 266.337
• Hs Code.: 2917209090
• European Community (EC) Number: 301-095-4
• DSSTox Substance ID: DTXSID40916772
• Nikkaji Number: J367.877F
• Mol file: 93981-13-6.mol

Synonyms:93981-13-6;Diethyl allyl-2-cyclopenten-1-ylmalonate;EINECS 301-095-4;DTXSID40916772;ZJKBNCDQDWUIOF-UHFFFAOYSA-N;NS00063265;Diethyl (cyclopent-2-en-1-yl)(prop-2-en-1-yl)propanedioate

Chemical Property of Diethyl allyl-2-cyclopenten-1-ylmalonate

Chemical Property:

• Vapor Pressure: 0.000183mmHg at 25°C
• Boiling Point: 329°Cat760mmHg
• Flash Point: 153.4°C
• PSA: 52.60000
• Density: 1.068g/cm³
• LogP: 2.78540
• XLogP3: 3.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 9
• Exact Mass: 266.15180918
• Heavy Atom Count: 19
• Complexity: 352

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCOC(=O)C(CC=C)(C1CCC=C1)C(=O)OCC

Technology Process of Diethyl allyl-2-cyclopenten-1-ylmalonate

There total 2 articles about Diethyl allyl-2-cyclopenten-1-ylmalonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclopenta-1,3-diene (542-92-7,25568-84-7,7313-32-8) → allyl-cyclopent-2-enyl-malonic acid diethyl ester (93981-13-6)

Guidance literature:

Multi-step reaction with 2 steps

1: HCl; diethyl ether / -5 °C

With hydrogenchloride; diethyl ether;

DOI:10.1021/ja01251a017

Reference yield:

2-cyclopenten-1-yl chloride (96-40-2) → allyl-cyclopent-2-enyl-malonic acid diethyl ester (93981-13-6)

Guidance literature:

DOI:10.1021/ja01251a017

upstream raw materials:

2-cyclopenten-1-yl chloride

cyclopenta-1,3-diene