FeRu(CO)5(P(C₆H₅)3)(((CH₃)2CH)NCHCHN(CH(CH₃)2))

Base Information

• Chemical Name: FeRu(CO)5(P(C₆H₅)3)(((CH₃)2CH)NCHCHN(CH(CH₃)2))
• CAS No.: 146401-04-9
• Molecular Formula: C₃₁H₃₁FeN₂O₅PRu
• Molecular Weight: 699.488
• Mol file: 146401-04-9.mol

Synonyms:FeRu(CO)5(P(C₆H₅)3)(((CH₃)2CH)NCHCHN(CH(CH₃)2))

Chemical Property of FeRu(CO)5(P(C₆H₅)3)(((CH₃)2CH)NCHCHN(CH(CH₃)2))

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of FeRu(CO)5(P(C₆H₅)3)(((CH₃)2CH)NCHCHN(CH(CH₃)2))

There total 1 articles about FeRu(CO)5(P(C₆H₅)3)(((CH₃)2CH)NCHCHN(CH(CH₃)2)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

FeRu(CO)6(σ-N,μ2-N`,η2-C=N`-1,4-di-isopropyl-1,4-diaza-1,3-butadiene) (90219-33-3) → FeRu(CO)5(P(C6H5)3)(((CH3)2CH)NCHCHN(CH(CH3)2)) (146401-04-9)

Guidance literature:

With P(C₆H₅)3; In hexane; (N2); stirred for about 30 min; used as solvent CH2Cl2 or benzene the react. time increased to several h; ppt.; filtered (celite); residue washed several time (hexane); extd. from filter (CH2Cl2); evapn.; crystn. (hexane/CH2Cl2; -20°C); elem. anal.;

DOI:10.1016/S0020-1693(00)86835-8

Reference yield:

FeRu(CO)5(P(C6H5)3)(((CH3)2CH)NCHCHN(CH(CH3)2)) (146401-04-9) → tricarbonylbis(triphenylphosphine)ruthenium(0) (20332-49-4,14741-36-7)

Guidance literature:

Multi-step reaction with 2 steps

1: P(C₆H₅)3; hydrogen / toluene

2: triphenylphosphine / not given

With P(C₆H₅)3; hydrogen; triphenylphosphine; In toluene;

DOI:10.1016/S0020-1693(00)86835-8

Reference yield:

FeRu(CO)5(P(C6H5)3)(((CH3)2CH)NCHCHN(CH(CH3)2)) (146401-04-9) → FeRu(CO)5(P(C6H5)3)(((CH3)2CH)NCH2CH2N(CH(CH3)2))

Guidance literature:

With hydrogen; In benzene-d6; (N2); high pressure (40 bar; hydrogen) for about 75 min; 110°C; 1H NMR;

DOI:10.1016/S0020-1693(00)86835-8

upstream raw materials:

FeRu(CO)6(σ-N,μ2-N`,η2-C=N`-1,4-di-isopropyl-1,4-diaza-1,3-butadiene)

Downstream raw materials:

tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾

FeRu(CO)5(P(CH₃)2(C₆H₅))(((CH₃)2CH)NCHCHN(CH(CH₃)2))