(η2,η2-1,4-cyclooctadiene)[(1,6,7,8,9-η)-10,22,25-triphenyl-22,25-dihydro(C70-D(5h(6)))[5,6]fulleren-7(10H)-yl]rhodium(I)

Base Information

Chemical Name:(η2,η2-1,4-cyclooctadiene)[(1,6,7,8,9-η)-10,22,25-triphenyl-22,25-dihydro(C70-D(5h(6)))[5,6]fulleren-7(10H)-yl]rhodium(I)
CAS No.:638132-45-3
Molecular Formula:C₉₆H₂₇Rh
Molecular Weight:1283.18
Hs Code.:

Synonyms:(η2,η2-1,4-cyclooctadiene)[(1,6,7,8,9-η)-10,22,25-triphenyl-22,25-dihydro(C70-D(5h(6)))[5,6]fulleren-7(10H)-yl]rhodium(I)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (η2,η2-1,4-cyclooctadiene)[(1,6,7,8,9-η)-10,22,25-triphenyl-22,25-dihydro(C70-D(5h(6)))[5,6]fulleren-7(10H)-yl]rhodium(I)

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (η2,η2-1,4-cyclooctadiene)[(1,6,7,8,9-η)-10,22,25-triphenyl-22,25-dihydro(C70-D(5h(6)))[5,6]fulleren-7(10H)-yl]rhodium(I)

There total 1 articles about (η2,η2-1,4-cyclooctadiene)[(1,6,7,8,9-η)-10,22,25-triphenyl-22,25-dihydro(C70-D(5h(6)))[5,6]fulleren-7(10H)-yl]rhodium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 244237-40-9
2,5,10-triphenyl-2,5,6,10-tetrahydro[70]fullerene

: 638132-45-3
(η2,η2-1,4-cyclooctadiene)[(1,6,7,8,9-η)-10,22,25-triphenyl-22,25-dihydro(C70-D(5h(6)))[5,6]fulleren-7(10H)-yl]rhodium(I)

Guidance literature:: With (CH₃)3COK; In tetrahydrofuran; under Ar or N2; soln. of 1.2 equiv of t-BuOK in THF added to soln. of C70Ph3H in THF at 25°C, Rh-complex (2 equiv) added in one portion at 28°C, stirred for 70 min; degassed hexane added, ppt. filtered off, washed with ether, hexane, water, dried in the air overnight;
DOI:10.1016/S0022-328X(03)00465-0