4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl

Base Information

• Chemical Name: 4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl
• CAS No.: 809285-99-2
• Molecular Formula: C₄₇H₅₂O₆
• Molecular Weight: 712.926
• Mol file: 809285-99-2.mol

Synonyms:4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl

Chemical Property of 4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl

There total 6 articles about 4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

[4-(4'-n-tetradecyloxybenzoyloxy)]benzoic acid (852561-82-1) + 4'-(benzyloxy)-1,1'-biphenyl-3-ol (809285-98-1) → 4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl (809285-99-2)

Guidance literature:

With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20 ℃;

DOI:10.1002/anie.200460549

Reference yield:

3-bromophenyl acetate (35065-86-2) → 4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl (809285-99-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 68 percent / Pd(PPh₃)4; aq. NaHCO₃ / 1,2-dimethoxy-ethane / 8 h / Heating

2: N,N'-dicyclohexylcarbodiimide; 4-N,N-dimethylaminopyridine / CH₂Cl₂ / 20 °C

With dmap; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydrogencarbonate; dicyclohexyl-carbodiimide; In 1,2-dimethoxyethane; dichloromethane;

DOI:10.1021/ja057685t

Reference yield:

[4-(benzyloxy)phenyl]boronic acid (146631-00-7) → 4'-benzyloxy-3-[4-(4'-n-tetradecyloxybenzoyloxy)benzoyloxy]biphenyl (809285-99-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 68 percent / Pd(PPh₃)4; aq. NaHCO₃ / 1,2-dimethoxy-ethane / 8 h / Heating

2: N,N'-dicyclohexylcarbodiimide; 4-N,N-dimethylaminopyridine / CH₂Cl₂ / 20 °C

With dmap; tetrakis(triphenylphosphine) palladium⁽⁰⁾; sodium hydrogencarbonate; dicyclohexyl-carbodiimide; In 1,2-dimethoxyethane; dichloromethane;

DOI:10.1021/ja057685t

upstream raw materials:

[4-(4'-n-tetradecyloxybenzoyloxy)]benzoic acid

4'-(benzyloxy)-1,1'-biphenyl-3-ol

3-bromophenyl acetate

[4-(benzyloxy)phenyl]boronic acid

Downstream raw materials:

C₅₉H₆₄O₁₀

C₅₈H₇₀O₁₀

C₆₅H₇₆O₁₀

3-[4-(4-n-tetradecyloxybenzoyloxy)benzoyloxy]-4'-(4''''-formylbenzoyloxy)biphenyl