C₄₈H₅₇NO₇SSi

Base Information

Chemical Name:C₄₈H₅₇NO₇SSi
CAS No.:1431117-01-9
Molecular Formula:C₄₈H₅₇NO₇SSi
Molecular Weight:820.135
Hs Code.:

C<sub>48</sub>H<sub>57</sub>NO<sub>7</sub>SSi

Synonyms:C₄₈H₅₇NO₇SSi

Suppliers and Price of C₄₈H₅₇NO₇SSi

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of C₄₈H₅₇NO₇SSi

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of C₄₈H₅₇NO₇SSi

There total 16 articles about C₄₈H₅₇NO₇SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 1431116-99-2
C₃₂H₃₉NO₇S

: 58479-61-1
tert-butylchlorodiphenylsilane

: 1431117-01-9
C₄₈H₅₇NO₇SSi

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃; for 1h;
DOI:10.1016/j.tet.2013.03.012

Reference yield:

: C₂₃H₃₁NO₇S

: 1431117-01-9
C₄₈H₅₇NO₇SSi

Guidance literature:: Multi-step reaction with 13 steps

1.1: 1H-imidazole / tetrahydrofuran / 24 h / 0 - 20 °C

2.1: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 0 - 20 °C

3.1: potassium iodide; sodium hydride / tetrahydrofuran / 6 h / 60 °C

4.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 20 °C

5.1: Dess-Martin periodane / dichloromethane / 1 h / 0 °C / Inert atmosphere

6.1: dichloromethane / 2 h / 20 °C / Inert atmosphere

7.1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / 78 °C / Inert atmosphere

8.1: titanium(IV) isopropylate; L-(+)-diisopropyl tartrate / dichloromethane / 0.5 h / -30 °C / Inert atmosphere

8.2: 15 h / -30 °C / Inert atmosphere

9.1: Dess-Martin periodane / dichloromethane / 1 h / 0 °C / Inert atmosphere

10.1: dichloromethane / 2 h / 20 °C / Inert atmosphere

11.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 7 h / -30 - 20 °C / Inert atmosphere

12.1: diisobutylaluminium hydride / dichloromethane; toluene / 0.67 h / -78 °C / Inert atmosphere

13.1: triethylamine; dmap / dichloromethane / 1 h / 20 °C

With 1H-imidazole; titanium(IV) isopropylate; dmap; lithium aluminium tetrahydride; L-(+)-diisopropyl tartrate; trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; Dess-Martin periodane; triethylamine; potassium iodide; In tetrahydrofuran; dichloromethane; toluene; 5.1: |Dess-Martin Oxidation / 6.1: |Wittig Olefination / 9.1: |Dess-Martin Oxidation / 10.1: |Wittig Olefination;
DOI:10.1016/j.tet.2013.03.012

Reference yield:

: C₃₉H₄₉NO₇SSi

: 1431117-01-9
C₄₈H₅₇NO₇SSi

Guidance literature:: Multi-step reaction with 12 steps

1.1: lithium aluminium tetrahydride / tetrahydrofuran / 3 h / 0 - 20 °C

2.1: potassium iodide; sodium hydride / tetrahydrofuran / 6 h / 60 °C

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 3 h / 20 °C

4.1: Dess-Martin periodane / dichloromethane / 1 h / 0 °C / Inert atmosphere

5.1: dichloromethane / 2 h / 20 °C / Inert atmosphere

6.1: diisobutylaluminium hydride / dichloromethane; toluene / 1 h / 78 °C / Inert atmosphere

7.1: titanium(IV) isopropylate; L-(+)-diisopropyl tartrate / dichloromethane / 0.5 h / -30 °C / Inert atmosphere

7.2: 15 h / -30 °C / Inert atmosphere

8.1: Dess-Martin periodane / dichloromethane / 1 h / 0 °C / Inert atmosphere

9.1: dichloromethane / 2 h / 20 °C / Inert atmosphere

10.1: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 7 h / -30 - 20 °C / Inert atmosphere

11.1: diisobutylaluminium hydride / dichloromethane; toluene / 0.67 h / -78 °C / Inert atmosphere

12.1: triethylamine; dmap / dichloromethane / 1 h / 20 °C

With titanium(IV) isopropylate; dmap; lithium aluminium tetrahydride; L-(+)-diisopropyl tartrate; trimethylsilyl trifluoromethanesulfonate; tetrabutyl ammonium fluoride; sodium hydride; diisobutylaluminium hydride; Dess-Martin periodane; triethylamine; potassium iodide; In tetrahydrofuran; dichloromethane; toluene; 4.1: |Dess-Martin Oxidation / 5.1: |Wittig Olefination / 8.1: |Dess-Martin Oxidation / 9.1: |Wittig Olefination;
DOI:10.1016/j.tet.2013.03.012