C₃₅H₅₀O₅Si₂

Base Information

Chemical Name:C₃₅H₅₀O₅Si₂
CAS No.:1261152-37-7
Molecular Formula:C₃₅H₅₀O₅Si₂
Molecular Weight:606.95
Hs Code.:

C<sub>35</sub>H<sub>50</sub>O<sub>5</sub>Si<sub>2</sub>

Synonyms:C₃₅H₅₀O₅Si₂

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Chemical Property of C₃₅H₅₀O₅Si₂

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Technology Process of C₃₅H₅₀O₅Si₂

There total 1 articles about C₃₅H₅₀O₅Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 1261152-36-6
C₃₅H₄₈O₄Si₂

: 1261152-37-7
C₃₅H₅₀O₅Si₂

Guidance literature:: C₃₅H₄₈O₄Si₂; With bis-(1,2-dimethylpropyl)borane; In tetrahydrofuran; at -78 - 0 ℃; for 144h; Inert atmosphere;

With dihydrogen peroxide; sodium hydroxide; In tetrahydrofuran; water; for 14h; stereoselective reaction;
DOI:10.1021/ja109533y

Reference yield: 100.0%

: 1261152-37-7
C₃₅H₅₀O₅Si₂

: 69739-34-0
t-butyldimethylsiyl triflate

: 1261152-38-8
C₄₁H₆₄O₅Si₃

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 25 ℃; Inert atmosphere;
DOI:10.1021/ja109533y

Reference yield:

: 1261152-37-7
C₃₅H₅₀O₅Si₂

: 1261152-35-5
C₇₀H₉₈O₉Si₃

Guidance literature:: Multi-step reaction with 26 steps

1.1: triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

2.1: 20 % Pd(OH)2/C; hydrogen / ethanol / 18 h / 25 °C / Inert atmosphere

3.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 0.17 h / -78 °C / Inert atmosphere

3.2: 1 h / -78 °C / Inert atmosphere

3.3: 2 h / -78 - 0 °C / Inert atmosphere

4.1: dichloromethane / 1.5 h / 25 °C / Inert atmosphere

5.1: 2,6-dimethylpyridine / dichloromethane / 14 h / 0 °C / Inert atmosphere

6.1: diisobutylaluminium hydride / dichloromethane / 1 h / -78 °C / Inert atmosphere

6.2: 16 h / 25 °C / Inert atmosphere

7.1: titanium(IV) isopropylate; diethyl (2S,3S)-tartrate / dichloromethane / 1 h / -25 °C / Inert atmosphere; Molecular sieve

7.2: 17 h / -20 °C / Inert atmosphere; Molecular sieve

8.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

9.1: dichloromethane / 14 h / 20 °C / Inert atmosphere

10.1: tetrabutyl ammonium fluoride / dichloromethane / 0.33 h / 0 °C / Inert atmosphere

11.1: pyridinium p-toluenesulfonate / dichloromethane / 25 - 40 °C / Inert atmosphere

12.1: lanthanum(lll) triflate / toluene / 6 h / 25 °C / Inert atmosphere

13.1: sodium tetrahydroborate; nickel (II) chloride hexahydrate / ethanol / 0 °C / Inert atmosphere

14.1: lithium aluminium tetrahydride / tetrahydrofuran; diethyl ether / 0.5 h / 25 °C / Inert atmosphere

15.1: sulfur trioxide pyridine complex; dimethyl sulfoxide; triethylamine / dichloromethane / 0 - 25 °C / Inert atmosphere

16.1: sodium hexamethyldisilazane / tetrahydrofuran; toluene / 0.17 h / 0 °C / Inert atmosphere

16.2: 0.33 h / 0 °C / Inert atmosphere

17.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / dichloromethane / 3 h / 0 °C / Inert atmosphere

18.1: dmap; 2-methyl-6-nitrobenzoic anhydride; triethylamine / toluene / 0.33 h / 25 °C / Inert atmosphere; Molecular sieve

18.2: 13 h / 25 °C / Inert atmosphere; Molecular sieve

19.1: p-toluenesulfonic acid monohydrate / methanol; dichloromethane / 0.67 h / 0 °C / Inert atmosphere

20.1: N,N,N,N,-tetramethylethylenediamine; titanium tetrachloride / tetrahydrofuran; dichloromethane / 0 - 25 °C / Inert atmosphere

20.2: 0.67 h / 25 °C / Inert atmosphere

21.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C / Inert atmosphere

22.1: bis(cyclohexanyl)borane / tetrahydrofuran / 6 h / 25 °C / Inert atmosphere

22.2: 20 h / 0 °C / Inert atmosphere

23.1: sodium hydrogencarbonate; Dess-Martin periodane / dichloromethane / 0 - 25 °C / Inert atmosphere

24.1: p-toluenesulfonic acid monohydrate / methanol; dichloromethane / 0.5 h / 0 °C / Inert atmosphere

25.1: zinc trifluoromethanesulfonate / dichloromethane / 16 h / 25 °C / Inert atmosphere

26.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / -78 - 30 °C / Inert atmosphere

26.2: -78 - 0 °C / Inert atmosphere

With 2,6-dimethylpyridine; titanium(IV) isopropylate; dmap; sodium tetrahydroborate; lithium aluminium tetrahydride; oxalyl dichloride; nickel (II) chloride hexahydrate; diethyl (2S,3S)-tartrate; N,N,N,N,-tetramethylethylenediamine; 20 % Pd(OH)2/C; bis(cyclohexanyl)borane; 2-methyl-6-nitrobenzoic anhydride; p-toluenesulfonic acid monohydrate; tetrabutyl ammonium fluoride; hydrogen; sodium hexamethyldisilazane; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; titanium tetrachloride; zinc trifluoromethanesulfonate; diisobutylaluminium hydride; sodium hydrogencarbonate; Dess-Martin periodane; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone; lanthanum(lll) triflate; In tetrahydrofuran; methanol; diethyl ether; ethanol; dichloromethane; toluene; 3.1: Swern oxidation / 3.2: Swern oxidation / 3.3: Swern oxidation / 4.1: Wittig reaction / 7.1: Sharpless epoxidation / 7.2: Sharpless epoxidation / 8.1: Parikh-Doering oxidation / 9.1: Wittig reaction / 15.1: Parikh-Doering oxidation / 16.1: Wittig reaction / 16.2: Wittig reaction / 22.1: Hydroboration reaction;
DOI:10.1021/ja109533y