5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose

Base Information

Chemical Name:5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose
CAS No.:1606127-87-0
Molecular Formula:C₂₃H₂₈O₇S
Molecular Weight:448.537
Hs Code.:

Synonyms:5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose

Suppliers and Price of 5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose

There total 4 articles about 5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1606127-86-9
5-O-benzyl-3-deoxy-1,2-O-isopropylidene-α-D-glucofuranose

: 98-59-9
p-toluenesulfonyl chloride

: 1606127-87-0
5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose

Guidance literature:: With pyridine; at 20 ℃; for 10h;
DOI:10.1016/j.tetasy.2014.03.005

Reference yield:

: 1606127-85-8
C₃₂H₄₀O₅Si

: 1606127-87-0
5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 2 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 20 °C

2: pyridine / 10 h / 20 °C

With pyridine; tetrabutyl ammonium fluoride; In tetrahydrofuran;
DOI:10.1016/j.tetasy.2014.03.005

Reference yield:

: 158226-41-6
6-O-tert-butyldiphenylsilyl-3-deoxy-1,2-O-isopropylidene-α-D-ribo-hexofuranose

: 1606127-87-0
5-O-benzyl-3-deoxy-1,2-O-isopropylidene-6-O-p-toluenesulphonyl-α-D-glucofuranose

Guidance literature:: Multi-step reaction with 3 steps

1.1: sodium hydride; tetra-(n-butyl)ammonium iodide / N,N-dimethyl-formamide / 1 h / 0 - 20 °C

1.2: 1 h / 50 °C

1.3: 2 h / 50 °C

2.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 20 °C

3.1: pyridine / 10 h / 20 °C

With pyridine; tetrabutyl ammonium fluoride; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1016/j.tetasy.2014.03.005