2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan

Base Information

• Chemical Name: 2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan
• CAS No.: 108943-81-3
• Molecular Formula: C₃₈H₃₈O₆
• Molecular Weight: 590.716
• Mol file: 108943-81-3.mol

Synonyms:2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan

Chemical Property of 2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan

There total 10 articles about 2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

furan (110-00-9) + O-(2,3,4,6-Tetra-O-benzyl-β-D-glucopyranosyl)-N,2,2-tris(4-chlorphenyl)acetimidat (74808-07-4) → 2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan (108943-81-3)

Guidance literature:

With zinc chloride diethyl ether; In dichloromethane; for 1h; Ambient temperature;

Reference yield: 78.0%

furan (110-00-9) + 2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate (74808-09-6) → 2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan (108943-81-3)

Guidance literature:

With zinc(II) chloride; In dichloromethane;

DOI:10.1016/j.tetlet.2011.10.041

Reference yield: 75.0%

furan (110-00-9) + 1-O-acetyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose (80300-30-7) → 2-(1'-deoxy-2',3',4',6'-tetra-O-benzyl-α-D-glucopyranosyl)furan (108943-81-3)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; 4 Angstroem MS; In acetonitrile; at -40 ℃; for 1h;

DOI:10.1016/S0040-4039(00)79320-8

upstream raw materials:

furan

1-O-acetyl-2,3,4,6-tetra-O-benzyl-D-glucopyranose

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl trichloroacetimidate

O-(2,3,4,6-Tetra-O-benzyl-β-D-glucopyranosyl)-N,2,2-tris(4-chlorphenyl)acetimidat

Downstream raw materials:

2-Methylthio-5-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)furan

2-Acetyl-5-(6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranosyl)furan

2-Acetyl-5-(6-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranosyl)furan

5-(1-Hydroxypropyl)-2-(2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl)furan