(C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3

Base Information

Chemical Name:(C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3
CAS No.:221121-79-5
Molecular Formula:C₁₆H₁₇FeNO₄
Molecular Weight:343.162
Hs Code.:

(C<sub>4</sub>H<sub>3</sub>OCHCHCHNC<sub>6</sub>H<sub>11</sub>)Fe(CO)3

Synonyms:(C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3

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Chemical Property of (C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3

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Technology Process of (C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3

There total 1 articles about (C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.6%

: 15321-51-4
diiron nonacarbonyl

: 221121-75-1
C₄H₃OCHCHCHNC₆H₁₁

: 221121-79-5
(C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3

Guidance literature:: In n-heptane; Ar-atmosphere; stirring Fe2(CO)9 with 1 equiv. of azadiene ligand at 50°C; evapn., dissoln. (CH2Cl2), chromy. (silica, petroleum:CH2Cl2 10:1), crystn. (petroleum:CH2Cl2 20:1, -20°C); elem. anal.;
DOI:10.1021/om980415h

Reference yield: 82.0%

: 221121-79-5
(C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3

: 2417-95-0
p-tolyllithium

: 349669-09-6
C₄H₃OCHCHCHNC₆H₁₁Fe(CO)2COC₆H₄CH₃

Guidance literature:: With Et₃OBF₄; In diethyl ether; to a soln. of complex in ether at -75°C was added ArLi with stirring, the mixt. was stirred for 4 h at -75 to -35°C, the soln. wasevapd. in vac. at -40°C, Et3OBF4 was added to CH2Cl2-soln. at -6 5°C, stirred for 2 h (N2); petroleum ether was added, extd. with petroleum ether-CH2Cl2, evapd., chromd. on alumina column at -20 to -30°C (petroleum ether-CH2Cl2), recrystd. from petroleum ether-CH2Cl2 at -80°C; elem. anal.;
DOI:10.1021/om010034v

Reference yield: 80.0%

: 221121-79-5
(C₄H₃OCHCHCHNC₆H₁₁)Fe(CO)3

: 10325-82-3
m-tolyllithium

: 349669-08-5
C₄H₃OCHCHCHNC₆H₁₁Fe(CO)2COC₆H₄CH₃

Guidance literature:: With Et₃OBF₄; In diethyl ether; to a soln. of complex in ether at -75°C was added ArLi with stirring, the mixt. was stirred for 4 h at -75 to -35°C, the soln. wasevapd. in vac. at -40°C, Et3OBF4 was added to CH2Cl2-soln. at -6 5°C, stirred for 2 h (N2); petroleum ether was added, extd. with petroleum ether-CH2Cl2, evapd., chromd. on alumina column at -20 to -30°C (petroleum ether-CH2Cl2), recrystd. from petroleum ether-CH2Cl2 at -80°C; elem. anal.;
DOI:10.1021/om010034v