allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Base Information

Chemical Name:allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside
CAS No.:1384536-81-5
Molecular Formula:C₄₀H₄₇Cl₃N₂O₁₆
Molecular Weight:918.176
Hs Code.:

allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Synonyms:allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside

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Chemical Property of allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside

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Technology Process of allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside

There total 2 articles about allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

: 1384536-77-9
3,4,6-tri-O-acetyl-2-amino-2-deoxy-1-O,2-N-[(2,2,2-trichloroethoxy)methylylidene]-α-D-glucopyranose

: 399036-09-0
allyl 2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside

: 1384536-81-5
allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: With sym-collidinium perchlorate; In dichloromethane; at 20 ℃; for 48h; Molecular sieve;
DOI:10.1016/j.carres.2012.03.026

Reference yield:

: 67124-60-1
3,4,6-Tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-α-D-glucopyranosyl bromide

: 1384536-81-5
allyl [3,4,6-tri-O-acetyl-2-deoxy-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-(1->4)-2-acetamido-6-O-benzoyl-3-O-benzyl-2-deoxy-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: silver perchlorate; triethylamine / dichloromethane; benzene / 0.5 h / -35 °C / Molecular sieve

2: sym-collidinium perchlorate / dichloromethane / 48 h / 20 °C / Molecular sieve

With silver perchlorate; triethylamine; sym-collidinium perchlorate; In dichloromethane; benzene;
DOI:10.1016/j.carres.2012.03.026