copper(II) 21-thiatetra(p-tolyl)porphyrin bicarbonate

Base Information

• Chemical Name: copper(II) 21-thiatetra(p-tolyl)porphyrin bicarbonate
• CAS No.: 109088-81-5
• Molecular Formula: C₄₉H₃₇CuN₃O₃S
• Molecular Weight: 811.463
• Mol file: 109088-81-5.mol

Synonyms:copper(II) 21-thiatetra(p-tolyl)porphyrin bicarbonate

Chemical Property of copper(II) 21-thiatetra(p-tolyl)porphyrin bicarbonate

Chemical Property:

Purity/Quality:

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Technology Process of copper(II) 21-thiatetra(p-tolyl)porphyrin bicarbonate

There total 2 articles about copper(II) 21-thiatetra(p-tolyl)porphyrin bicarbonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

hydrated copper(II) chloride + meso-5,10,15,20-tetra(p-tolyl)-21-thiaporphyrin → copper(II) 21-thiatetra(p-tolyl)porphyrin bicarbonate (109088-81-5)

Guidance literature:

With Na₂CO₃; In chloroform; a mixture of 21-thiatetra-p-tolylporphyrin (STTPH) in CHCl3 and an ethanolic soln. of CuCl2-hydrate was boiled in presence of triethyl orthoformate and solid Na2CO3 for 0.5 h, evaporation of the solvent;; chromy. on neutral alumina with CH2Cl2 as eluent, recrystd. from CH2Cl2/toluene;;

DOI:10.1021/ja00248a067

Reference yield:

meso-5,10,15,20-tetra(p-tolyl)-21-thiaporphyrin + copper dichloride → copper(II) 21-thiatetra(p-tolyl)porphyrin bicarbonate (109088-81-5)

Guidance literature:

With 2,3,5-trimethyl-pyridine; potassium carbonate; In methanol; chloroform; a soln. of CuCl2 in methanol mixed with a soln. of organic compound in CHCl3;