(5-bromo-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Base Information

• Chemical Name: (5-bromo-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)
• CAS No.: 1138342-08-1
• Molecular Formula: C₅₉H₇₁BrN₄SiZn
• Molecular Weight: 1009.62
• Mol file: 1138342-08-1.mol

Synonyms:(5-bromo-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Chemical Property of (5-bromo-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (5-bromo-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

There total 1 articles about (5-bromo-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(5-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) (1138342-07-0) → (5-bromo-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) (1138342-08-1)

Guidance literature:

With N-Bromosuccinimide; In pyridine; chloroform; at 25 ℃; Inert atmosphere;

DOI:10.1002/chem.200801572

Reference yield: 67.0%

(5-bromo-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II) (1138342-08-1) + N,N-bis(4-hexylphenyl)amine (419566-33-9) → (5-bis(4-hexylphenyl)amino-15-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Guidance literature:

With palladium diacetate; sodium hydride; bis[2-(diphenylphosphino)phenyl] ether; In toluene; for 5h; Reflux;

Reference yield: 62.0%

N,N-bis(4-hexylphenyl)amine (419566-33-9) + C59H71BrN4SiZn (1138342-08-1) → zinc(II) 5,15-bis(3,5-di-tert-butylphenyl)-10-(bis(4-hexylphenyl)amino)-20-(triisoproylsilylethynyl)porphyrin (1201915-92-5)

Guidance literature:

N,N-bis(4-hexylphenyl)amine; With sodium hydride; In tetrahydrofuran; for 0.0833333h; Inert atmosphere;

C₅₉H₇₁BrN₄SiZn; With palladium diacetate; bis[2-(diphenylphosphino)phenyl] ether; In tetrahydrofuran; for 5h; Inert atmosphere; Reflux;

DOI:10.1039/b919645e

upstream raw materials:

(5-(triisopropylsilyl)ethynyl-10,20-bis(3,5-di-tert-butylphenyl)porphyrinato)zinc(II)

Downstream raw materials:

Zinc(II) 5,15-Bis(3,5-di-tert-butylphenyl)-10-(bis(4-tert-butylphenyl)amino)-20-(triisopropylsilylethynyl)porphyrin

C₇₉H₉₅N₅SiZn

zinc(II) 5,15-bis(3,5-di-tert-butylphenyl)-10-(bis(4-hexylphenyl)amino)-20-(triisoproylsilylethynyl)porphyrin

C₈₇H₁₁₃N₅SiZn