2(3H)-Furanone, 5-(3Z)-3-hexenyldihydro-5-methyl-

Base Information

Chemical Name:2(3H)-Furanone, 5-(3Z)-3-hexenyldihydro-5-methyl-
CAS No.:70851-61-5
Molecular Formula:C₁₁H₁₈O₂
Molecular Weight:182.263
Hs Code.:
European Community (EC) Number:274-942-8,238-127-0
DSSTox Substance ID:DTXSID701216879
Nikkaji Number:J1.936.389I,J216.926F
Metabolomics Workbench ID:47252
Mol file:70851-61-5.mol

Synonyms:Cis-jasmonolactone;(E)-3-Hexenyldihydro-5-methylfuran-2(3H)-one;EINECS 238-127-0;14252-84-7;(E)-3-Hexenyl)dihydro-5-methylfuran-2(3H)-one;4-Hydroxy-4-methyl-7-decenoic acid gamma-lactone;waxy lactone;2(3H)-Furanone, 5-(3-hexenyl)dihydro-5-methyl-, (E)-;4-Methyl-cis-decene gamma-lactone;Lactone of cis Jasmone;4-Hydroxy-4-methyl-7-cis-decenoic acid lactone;70851-61-5;(Z)-Dihydro-5-(3-hexenyl)-5-methyl-2(3H)-furanone;2(3H)-Furanone, 5-(3Z)-3-hexenyldihydro-5-methyl-;2(3H)-Furanone, dihydro-5-(3-hexenyl)-5-methyl-, (Z)-;SCHEMBL1532400;SCHEMBL3110275;FEMA 3937;NIKDJTTZUYNCMM-SNAWJCMRSA-N;DTXSID701216879;LS-70449;4-Methyl-4-hydroxy-7-decenoic acid lactone;5-[(Z)-hex-3-enyl]-5-methyloxolan-2-one;5-[(3E)-hex-3-en-1-yl]-5-methyloxolan-2-one;5-(3Z)-3-Hexenyldihydro-5-methyl-2(3H)-Furanone;5-(3-hexenyl)dihydro-5-methyl-(z)-2(3h)-furanone;5-[(E)-3-Hexenyl]dihydro-5-methyl-2(3H)-furanone;5-(3Z)-3-Hexen-1-yldihydro-5-methyl-2(3H)-Furanone;Dihydro-5-(3-hexenyl)-5-methyl-(Z)-2(3H)-Furanone

Suppliers and Price of 2(3H)-Furanone, 5-(3Z)-3-hexenyldihydro-5-methyl-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
4-Hydroxy-4-methyl-7-cis-decenoic acid γ-lactone ≥95%cisisomer
100g-k
$ 159.00

Sigma-Aldrich
4-Hydroxy-4-methyl-7-cis-decenoic acid γ-lactone ≥95%cisisomer
sample-k
$ 40.00

Sigma-Aldrich
4-Hydroxy-4-methyl-7-cis-decenoic acid γ-lactone ≥95%cisisomer
1kg-k
$ 978.00

American Custom Chemicals Corporation
CIS-JASMONOLACTONE 95.00%
5MG
$ 501.75

Total 14 raw suppliers

Chemical Property of 2(3H)-Furanone, 5-(3Z)-3-hexenyldihydro-5-methyl-

Chemical Property:

Vapor Pressure:0.00352mmHg at 25°C
Refractive Index:n20/D1.466
Boiling Point:281.6°C at 760 mmHg
Flash Point:113.2°C
PSA：26.30000
Density:0.966 g/mL at 25 °C
LogP:2.82850
XLogP3:2.6
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:182.130679813
Heavy Atom Count:13
Complexity:208

Purity/Quality:

99.5%MIN ^*data from raw suppliers

4-Hydroxy-4-methyl-7-cis-decenoic acid γ-lactone ≥95%cisisomer ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCC=CCCC1(CCC(=O)O1)C
Isomeric SMILES:CC/C=C/CCC1(CCC(=O)O1)C

Technology Process of 2(3H)-Furanone, 5-(3Z)-3-hexenyldihydro-5-methyl-

There total 7 articles about 2(3H)-Furanone, 5-(3Z)-3-hexenyldihydro-5-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: cis-4-methyl-4-hydroxy-7-decene-2-ynoic acid methyl ester

: 70851-61-5
cis-jasmone lactone

Guidance literature:: With sodium tetrahydroborate; copper(l) chloride; In methanol; at -50 ℃; for 5h; Concentration;

Reference yield:

: 14252-84-7,70851-61-5
γ-Methyl-γ-(hex-3t-enyl)-butyrolacton

Guidance literature:: γ-Methyl-γ-(hex-3t-enyl)-paraconsaeure, KHSO4, 230-250grad, neben nicht aufgetrenntem Gemisch v. 4-Methyl-deca-3,7-diencarbonsaeure (VIIIa) u. 4-Methyl-4,7-dien-carbonsaeure (IXb);

Reference yield:

: 928-96-1
(Z)-3-Hexen-1-ol

: 70851-61-5
cis-jasmone lactone

Guidance literature:: Multi-step reaction with 5 steps

1.1: N,N-dimethyl-formamide; thionyl chloride / dimethyl sulfoxide / 3 h / 5 - 25 °C

2.1: magnesium; iodine / tetrahydrofuran / 2 h / Reflux

3.1: tetrahydrofuran / -60 - -20 °C

4.1: n-butyllithium / tetrahydrofuran; hexane / 0.25 h / -78 °C

4.2: -78 - 20 °C

5.1: copper(l) chloride; sodium tetrahydroborate / methanol / 5 h / -50 °C

With sodium tetrahydroborate; n-butyllithium; thionyl chloride; iodine; magnesium; N,N-dimethyl-formamide; copper(l) chloride; In tetrahydrofuran; methanol; hexane; dimethyl sulfoxide;