methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

Base Information

Chemical Name:methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside
CAS No.:352438-39-2
Molecular Formula:C₃₂H₃₀O₁₁
Molecular Weight:590.584
Hs Code.:

Synonyms:methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

Suppliers and Price of methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

There total 2 articles about methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 26532-10-5
methyl 2,3-anhydro-α-D-lyxofuranoside

: 352438-38-1
p-tolyl 2,3,5-tri-O-benzoyl-1-thio-α-D-arabinofuranoside

: 352438-39-2
methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

Guidance literature:: With N-iodo-succinimide; silver trifluoromethanesulfonate; In dichloromethane; at 0 ℃; for 0.5h;
DOI:10.1021/jo001747a

Reference yield:

: 2,3,5 tri-O-benzoyl-α-D-arabinofuranoside

: 352438-39-2
methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / BF₃*Et₂O / CH₂Cl₂ / 5 h / 20 °C

2: 88 percent / N-iodosuccinimide; silfer triflate / CH₂Cl₂ / 0.5 h / 0 °C

With N-iodo-succinimide; boron trifluoride diethyl etherate; silver trifluoromethanesulfonate; In dichloromethane;
DOI:10.1021/jo001747a

Reference yield:

: 352438-39-2
methyl 5-O-(2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

: methyl 5-O-(2,3-anhydro-5-O-benzoyl-α-D-lyxofuranosyl)-2,3-anhydro-α-D-lyxofuranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 97 percent / NaOMe / CH₂Cl₂; methanol / 6 h / 20 °C

2: 91 percent / Ph₃P; diisopropylazodicarboxylate / tetrahydrofuran / 1 h / 0 - 20 °C

With di-isopropyl azodicarboxylate; sodium methylate; triphenylphosphine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/jo001747a