C₆₉H₇₄O₁₁SSi

Base Information

Chemical Name:C₆₉H₇₄O₁₁SSi
CAS No.:676609-81-7
Molecular Formula:C₆₉H₇₄O₁₁SSi
Molecular Weight:1139.49
Hs Code.:

C<sub>69</sub>H<sub>74</sub>O<sub>11</sub>SSi

Synonyms:C₆₉H₇₄O₁₁SSi

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Chemical Property of C₆₉H₇₄O₁₁SSi

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Technology Process of C₆₉H₇₄O₁₁SSi

There total 24 articles about C₆₉H₇₄O₁₁SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 676609-68-0
C₆₉H₇₄O₉SSi

: 676609-81-7
C₆₉H₇₄O₁₁SSi

: 676609-96-4
C₆₉H₇₄O₁₀SSi

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -15 ℃; for 3h;
DOI:10.1021/ol0364475

Reference yield:

: 676609-96-4
C₆₉H₇₄O₁₀SSi

: 676609-81-7
C₆₉H₇₄O₁₁SSi

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -15 ℃; for 7.5h;
DOI:10.1021/ol0364475

Reference yield:

: 939-26-4
2-bromomethylnaphthyl bromide

: 676609-81-7
C₆₉H₇₄O₁₁SSi

Guidance literature:: Multi-step reaction with 12 steps

1.1: 89 percent / NaH; TBAI / tetrahydrofuran / 3 h / 45 °C

2.1: aq. HCl / methanol; tetrahydrofuran / 25 h / 20 °C

3.1: 241 mg / 2,6-lutidine / CH₂Cl₂ / 0.17 h / 0 °C

4.1: 91 percent / CSA / tetrahydrofuran; methanol / 0.5 h / -5 °C

5.1: 41.5 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / 2 h / -60 - -45 °C

6.1: t-BuOK / tetrahydrofuran / 0.5 h / 0 °C

6.2: 36.2 mg / tetrahydrofuran / 0.83 h / 0 - 20 °C

7.1: 30.0 mg / TBAF / tetrahydrofuran / 1 h / 20 °C

8.1: AgOTf; 2,6-di-tert-butyl-4-methylpyridine / CH₂Cl₂ / 0.25 h / -50 °C

8.2: 60.2 mg / CH₂Cl₂ / 1 h / -50 - -30 °C

9.1: 54.1 mg / TBAF / tetrahydrofuran / 0.5 h / 20 °C

10.1: 92 percent / ((Mes)2N₂C₃H₄)Ru(=CHPH)Cl₂(PCy₃) / CH₂Cl₂ / 2 h / 20 °C

11.1: 100 percent / imidazole / dimethylformamide / 12 h / 20 °C

12.1: m-CPBA / CH₂Cl₂ / 3 h / -15 °C

With 1H-imidazole; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; 2,6-dimethylpyridine; hydrogenchloride; 2,6-di-tert-butyl-4-methylpyridine; oxalyl dichloride; camphor-10-sulfonic acid; potassium tert-butylate; tetrabutyl ammonium fluoride; silver trifluoromethanesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; dimethyl sulfoxide; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide; 5.1: Swern oxidation / 6.2: Wittig reaction;
DOI:10.1021/ol0364475