((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde

Base Information

Chemical Name:((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde
CAS No.:771531-61-4
Molecular Formula:C₁₄H₂₈O₂Si
Molecular Weight:256.461
Hs Code.:

Synonyms:((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde

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Chemical Property of ((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde

Chemical Property:

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Technology Process of ((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde

There total 5 articles about ((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: (E)-4-((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-but-2-enoic acid methyl ester

: 771531-61-4
((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde

Guidance literature:: (E)-4-((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-but-2-enoic acid methyl ester; With ozone; In dichloromethane; at -78 ℃;

With triphenylphosphine; In dichloromethane; at -78 - 20 ℃;
DOI:10.1002/chem.200400407

Reference yield:

: 771531-59-0
4-((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-butyric acid methyl ester

: 771531-61-4
((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1.1: HMPA; LDA / tetrahydrofuran / 1.5 h / -78 °C

1.2: 89 percent / tetrahydrofuran / 0.5 h / -78 °C

2.1: 95 percent / aq. H₂O₂ / CH₂Cl₂ / 0.33 h / 25 °C

3.1: O₃ / CH₂Cl₂ / -78 °C

3.2: 93 percent / PPh₃ / CH₂Cl₂ / -78 - 20 °C

With N,N,N,N,N,N-hexamethylphosphoric triamide; dihydrogen peroxide; ozone; lithium diisopropyl amide; In tetrahydrofuran; dichloromethane;
DOI:10.1002/chem.200400407

Reference yield:

: 771531-79-4
2-Phenylselanyl-4-((1S,6S)-2,2,6-trimethyl-6-trimethylsilanyloxy-cyclohexyl)-butyric acid methyl ester

: 771531-61-4
((1S,6S)-2,2,6-Trimethyl-6-trimethylsilanyloxy-cyclohexyl)-acetaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1.1: 95 percent / aq. H₂O₂ / CH₂Cl₂ / 0.33 h / 25 °C

2.1: O₃ / CH₂Cl₂ / -78 °C

2.2: 93 percent / PPh₃ / CH₂Cl₂ / -78 - 20 °C

With dihydrogen peroxide; ozone; In dichloromethane;
DOI:10.1002/chem.200400407