1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene

Base Information

Chemical Name:1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene
CAS No.:582299-94-3
Molecular Formula:C₄₇H₃₀F₆N₄S₂
Molecular Weight:828.904
Hs Code.:

Synonyms:1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene

Suppliers and Price of 1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene

There total 6 articles about 1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: 559-40-0
octaperfluorocyclopentene

: 582300-07-0
4-[4-(4-bromo-5-methyl-thiophen-2-yl)-phenyl]-2,2'-bipyridine

: 582299-94-3
1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene

Guidance literature:: 4-[4-(4-bromo-5-methyl-thiophen-2-yl)-phenyl]-2,2'-bipyridine; With n-butyllithium; In tetrahydrofuran; at -78 ℃;

octaperfluorocyclopentene; In tetrahydrofuran;
DOI:10.2533/000942903777679569

Reference yield:

: 554-14-3
2-Methylthiophene

: 582299-94-3
1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene

Guidance literature:: Multi-step reaction with 4 steps

1.1: 65 percent / Br₂; AcOH

2.1: BuLi / tetrahydrofuran / -78 °C

2.2: 40 percent / B(OMe)3

3.1: 69 percent / Pd(Ph₃P)4; aq. Na₂CO₃ / tetrahydrofuran / 24 h / Heating

4.1: BuLi / tetrahydrofuran / -78 °C

4.2: 30 percent / tetrahydrofuran

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; bromine; sodium carbonate; acetic acid; In tetrahydrofuran; 3.1: Suzuki cross-coupling;
DOI:10.2533/000942903777679569

Reference yield:

: 29421-73-6
3,5-dibromo-2-methylthiophene

: 582299-94-3
1,2-bis(5-(4'-(4''-[2,2']-bipyridylphenyl)-2-methylthiophen-3-yl))perfluorocyclopentene

Guidance literature:: Multi-step reaction with 3 steps

1.1: BuLi / tetrahydrofuran / -78 °C

1.2: 40 percent / B(OMe)3

2.1: 69 percent / Pd(Ph₃P)4; aq. Na₂CO₃ / tetrahydrofuran / 24 h / Heating

3.1: BuLi / tetrahydrofuran / -78 °C

3.2: 30 percent / tetrahydrofuran

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; sodium carbonate; In tetrahydrofuran; 2.1: Suzuki cross-coupling;
DOI:10.2533/000942903777679569