(5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane

Base Information

Chemical Name:(5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane
CAS No.:1615198-69-0
Molecular Formula:C₃₃H₅₂O₃Si
Molecular Weight:524.86
Hs Code.:

Synonyms:(5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane

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Chemical Property of (5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane

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Technology Process of (5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane

There total 7 articles about (5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 99493-58-0
(4R)-tridec-1-en-4-ol

: 1615198-69-0
(5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane

Guidance literature:: Multi-step reaction with 7 steps

1: dmap; 1H-imidazole / dichloromethane / 4 h / 0 - 20 °C / Inert atmosphere

2: dimethyl sulfide borane / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

3: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 3 h / 20 °C / Inert atmosphere

4: dmap; triethylamine; N,O-dimethylhydroxylamine*hydrochloride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 6 h / 20 °C / Inert atmosphere

5: vinyl magnesium bromide / tetrahydrofuran / 2 h / -78 °C / Inert atmosphere

6: (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; dimethyl sulfide borane / tetrahydrofuran; toluene / 6 h / -78 °C / Inert atmosphere

7: N-ethyl-N,N-diisopropylamine; tetra-(n-butyl)ammonium iodide / dichloromethane / 12 h / 20 °C / Inert atmosphere

With 1H-imidazole; dmap; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; vinyl magnesium bromide; N,O-dimethylhydroxylamine*hydrochloride; dimethyl sulfide borane; tetra-(n-butyl)ammonium iodide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; N-ethyl-N,N-diisopropylamine; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; dichloromethane; water; toluene;
DOI:10.1016/j.tet.2014.05.021

Reference yield:

: 1615198-64-5
(R)-4-(tert-butyldiphenylsilyloxy)tridecan-1-ol

: 1615198-69-0
(5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane

Guidance literature:: Multi-step reaction with 5 steps

1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 3 h / 20 °C / Inert atmosphere

2: dmap; triethylamine; N,O-dimethylhydroxylamine*hydrochloride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 6 h / 20 °C / Inert atmosphere

3: vinyl magnesium bromide / tetrahydrofuran / 2 h / -78 °C / Inert atmosphere

4: (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; dimethyl sulfide borane / tetrahydrofuran; toluene / 6 h / -78 °C / Inert atmosphere

5: N-ethyl-N,N-diisopropylamine; tetra-(n-butyl)ammonium iodide / dichloromethane / 12 h / 20 °C / Inert atmosphere

With dmap; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; vinyl magnesium bromide; N,O-dimethylhydroxylamine*hydrochloride; dimethyl sulfide borane; tetra-(n-butyl)ammonium iodide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; N-ethyl-N,N-diisopropylamine; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; dichloromethane; water; toluene;
DOI:10.1016/j.tet.2014.05.021

Reference yield:

: (R)-tert-butyldiphenyl(tridec-1-en-4-yloxy)silane

: 1615198-69-0
(5R,8R)-11,11-dimethyl-8-nonyl-10,10-diphenyl-5-vinyl-2,4,9-trioxa-10-siladodecane

Guidance literature:: Multi-step reaction with 6 steps

1: dimethyl sulfide borane / tetrahydrofuran / 2 h / 0 °C / Inert atmosphere

2: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 3 h / 20 °C / Inert atmosphere

3: dmap; triethylamine; N,O-dimethylhydroxylamine*hydrochloride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 6 h / 20 °C / Inert atmosphere

4: vinyl magnesium bromide / tetrahydrofuran / 2 h / -78 °C / Inert atmosphere

5: (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; dimethyl sulfide borane / tetrahydrofuran; toluene / 6 h / -78 °C / Inert atmosphere

6: N-ethyl-N,N-diisopropylamine; tetra-(n-butyl)ammonium iodide / dichloromethane / 12 h / 20 °C / Inert atmosphere

With dmap; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; vinyl magnesium bromide; N,O-dimethylhydroxylamine*hydrochloride; dimethyl sulfide borane; tetra-(n-butyl)ammonium iodide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; N-ethyl-N,N-diisopropylamine; (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole; In tetrahydrofuran; dichloromethane; water; toluene;
DOI:10.1016/j.tet.2014.05.021