C₃₇H₅₆O₆Si₂

Base Information

• Chemical Name: C₃₇H₅₆O₆Si₂
• CAS No.: 1350544-17-0
• Molecular Formula: C₃₇H₅₆O₆Si₂
• Molecular Weight: 653.019
• Mol file: 1350544-17-0.mol

Synonyms:C₃₇H₅₆O₆Si₂

Chemical Property of C₃₇H₅₆O₆Si₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₃₇H₅₆O₆Si₂

There total 8 articles about C₃₇H₅₆O₆Si₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

C37H56O5Si2 (1350544-16-9) → C37H56O6Si2 (1350544-17-0)

Guidance literature:

With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; at -78 - -5 ℃; for 7h; Inert atmosphere;

DOI:10.1021/ol202728v

Reference yield:

C24H36O5Si (1350544-09-0) → C37H56O6Si2 (1350544-17-0)

Guidance literature:

Multi-step reaction with 7 steps

1.1: titanium tetrachloride / toluene / 1.17 h / -78 °C / Inert atmosphere

1.2: 3.5 h / -78 - 5 °C

2.1: 1,1,1,3,3,3-hexamethyl-disilazane; sodium iodide / acetonitrile / 3 h / 82 °C / Inert atmosphere

3.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / 3 h / 23 °C / Inert atmosphere

4.1: diethylzinc / tetrahydrofuran; toluene / 0.5 h / -78 °C / Inert atmosphere

4.2: 0.67 h / -78 - 0 °C / Inert atmosphere

4.3: 0.42 h / -78 - -20 °C / Inert atmosphere

5.1: cerium(III) chloride; lithium chloride / diethyl ether / 3.25 h / -78 °C / Inert atmosphere

5.2: 2 h / -78 - 0 °C / Inert atmosphere

6.1: pyridinium p-toluenesulfonate / benzene / 4.5 h / 23 °C / Inert atmosphere

7.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 7 h / -78 - -5 °C / Inert atmosphere

With cerium(III) chloride; diethylzinc; pyridinium p-toluenesulfonate; titanium tetrachloride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; 1,1,1,3,3,3-hexamethyl-disilazane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium iodide; lithium chloride; In tetrahydrofuran; diethyl ether; dichloromethane; toluene; acetonitrile; benzene; 1.1: Diels-Alder reaction / 1.2: Diels-Alder reaction;

DOI:10.1021/ol202728v

Reference yield:

C24H38O5Si → C37H56O6Si2 (1350544-17-0)

Guidance literature:

Multi-step reaction with 8 steps

1.1: sulfur trioxide pyridine complex / dichloromethane; dimethyl sulfoxide / 1.5 h / 0 °C / Inert atmosphere

2.1: titanium tetrachloride / toluene / 1.17 h / -78 °C / Inert atmosphere

2.2: 3.5 h / -78 - 5 °C

3.1: 1,1,1,3,3,3-hexamethyl-disilazane; sodium iodide / acetonitrile / 3 h / 82 °C / Inert atmosphere

4.1: 2,3-dicyano-5,6-dichloro-p-benzoquinone / 3 h / 23 °C / Inert atmosphere

5.1: diethylzinc / tetrahydrofuran; toluene / 0.5 h / -78 °C / Inert atmosphere

5.2: 0.67 h / -78 - 0 °C / Inert atmosphere

5.3: 0.42 h / -78 - -20 °C / Inert atmosphere

6.1: cerium(III) chloride; lithium chloride / diethyl ether / 3.25 h / -78 °C / Inert atmosphere

6.2: 2 h / -78 - 0 °C / Inert atmosphere

7.1: pyridinium p-toluenesulfonate / benzene / 4.5 h / 23 °C / Inert atmosphere

8.1: sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 7 h / -78 - -5 °C / Inert atmosphere

With cerium(III) chloride; diethylzinc; sulfur trioxide pyridine complex; pyridinium p-toluenesulfonate; titanium tetrachloride; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; 1,1,1,3,3,3-hexamethyl-disilazane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium iodide; lithium chloride; In tetrahydrofuran; diethyl ether; dichloromethane; dimethyl sulfoxide; toluene; acetonitrile; benzene; 1.1: Parikh-Doering oxidation / 2.1: Diels-Alder reaction / 2.2: Diels-Alder reaction;

DOI:10.1021/ol202728v

upstream raw materials:

C₂₄H₃₆O₅Si

C₂₈H₄₂O₅Si

C₃₁H₅₀O₅Si₂

C₂₈H₄₀O₅Si

Downstream raw materials:

C₂₉H₄₆O₆Si

C₂₉H₄₄O₆Si