(2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane

Base Information

Chemical Name:(2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane
CAS No.:116782-04-8
Molecular Formula:C₂₀H₃₀O₆
Molecular Weight:366.455
Hs Code.:

Synonyms:(2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane

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Chemical Property of (2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane

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Technology Process of (2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane

There total 3 articles about (2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 116700-83-5
(3R,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-<(trimethylsilyl)methyl>-3-<3-acetoxy-2-(acetoxymethyl)prop-1-en-1-yl>cyclohex-1-ene

: 116782-04-8
(2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane

Guidance literature:: With trifluoroacetic acid; In dichloromethane; for 48h; Ambient temperature;
DOI:10.1021/ja00232a027

Reference yield:

: C₂₇H₅₂O₅Si₂

: 116782-04-8
(2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / tetrahydrofuran / 0 - 20 °C

2: bis(acetylacetonate)nickel(II) / tetrahydrofuran

3: iron(III) chloride; acetic anhydride

With iron(III) chloride; bis(acetylacetonate)nickel(II); acetic anhydride; sodium hydride; In tetrahydrofuran;
DOI:10.1021/acs.joc.0c00344

Reference yield:

: 116724-52-8
(3SR,4RS)-1-<(diethoxyphosphoryl)oxy>-2-(methoxycarbonyl)-4-(1-methylethyl)-3-<3-(tert-butyldimethylsiloxy)-2-<(tert-butyldimethylsiloxy)methyl>prop-1-en-1-yl>cyclohex-1-ene

: 116782-04-8
(2SR,3RS,4RS)-2-(methoxycarbonyl)-4-(1-methylethyl)-1-methylene-3-<3-acetoxy-2-(acetoxymethyl)propen-1-yl>cyclohexane

Guidance literature:: Multi-step reaction with 2 steps

1: bis(acetylacetonate)nickel(II) / tetrahydrofuran

2: iron(III) chloride; acetic anhydride

With iron(III) chloride; bis(acetylacetonate)nickel(II); acetic anhydride; In tetrahydrofuran;
DOI:10.1021/acs.joc.0c00344