methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate

Base Information

Chemical Name:methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate
CAS No.:197726-20-8
Molecular Formula:C₂₉H₄₇NO₄Si
Molecular Weight:501.782
Hs Code.:

Synonyms:methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate

Suppliers and Price of methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate

There total 8 articles about methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1501-26-4
methyl 4-(chlorocarbonyl)butyrate

: 197725-65-8
3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylamine

: 197726-20-8
methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate

Guidance literature:: With triethylamine; In dichloromethane; at 0 ℃; for 1h;
DOI:10.1016/S0968-0896(97)00090-4

Reference yield:

: 2809-67-8
oct-2-yne

: 197726-20-8
methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) t-BuLi, 2.) triisopropylborate

2: 95 percent / imidazole / dimethylformamide / 0.5 h / 25 °C

3: 100 percent / H₂, quinoline / 5percent Pd(2.7percent Pb)-CaCO₃ / ethanol / 0.5 h / 25 °C

4: 100 percent / aq. NaOH / tetrahydrofuran; methanol / 16 h / 25 °C

5: 100 percent / Et₃N / CH₂Cl₂ / 1 h / 0 °C

With 1H-imidazole; quinoline; sodium hydroxide; Triisopropyl borate; hydrogen; tert.-butyl lithium; triethylamine; Pd(2.7 percent Pb)-CaCO₃; In tetrahydrofuran; methanol; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(97)00090-4

Reference yield:

: 53663-37-9
3-aminobenzaldehyde dimethyl acetal

: 197726-20-8
methyl-4-[3-(3-tert-butyldimethylsilyloxy-1E,5Z-undecadienyl)phenylaminocarbonyl]butanoate

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) Et₃N, 2.) DL-camphorsulfonic acid / 1.) CH₂Cl₂, 0 deg C, 30 min, 2.) acetone, 25 deg C, 16 h

2: 1.) NaOMe, 2.) aq. HCl / 1.) DMF, MeOH, 60 deg C, 30 min, 2.) THF, 25 deg C, 1 h

3: 1.) t-BuLi, 2.) triisopropylborate

4: 95 percent / imidazole / dimethylformamide / 0.5 h / 25 °C

5: 100 percent / H₂, quinoline / 5percent Pd(2.7percent Pb)-CaCO₃ / ethanol / 0.5 h / 25 °C

6: 100 percent / aq. NaOH / tetrahydrofuran; methanol / 16 h / 25 °C

7: 100 percent / Et₃N / CH₂Cl₂ / 1 h / 0 °C

With 1H-imidazole; quinoline; hydrogenchloride; sodium hydroxide; Triisopropyl borate; camphor-10-sulfonic acid; hydrogen; tert.-butyl lithium; sodium methylate; triethylamine; Pd(2.7 percent Pb)-CaCO₃; In tetrahydrofuran; methanol; ethanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(97)00090-4