N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine

Base Information

Chemical Name:N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine
CAS No.:1207629-92-2
Molecular Formula:C₂₀H₂₀ClN₃
Molecular Weight:337.852
Hs Code.:

N<sub>1</sub>-(2-aminophenyl)-N<sub>2</sub>-(2-chlorophenyl)-N<sub>1</sub>,N<sub>2</sub>-dimethylbenzene-1,2-diamine

Synonyms:N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine

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Chemical Property of N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine

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Technology Process of N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine

There total 7 articles about N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1207629-91-1
N₁-(2-chlorophenyl)-N₁,N₂-dimethyl-N₂-(2-nitrophenyl)benzene-1,2-diamine

: 1207629-92-2
N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine

Guidance literature:: With potassium borohydride; copper(l) chloride; In methanol; at 20 ℃; Inert atmosphere;
DOI:10.1021/jo1017074

Reference yield:

: 1207629-88-6
N₁-(2-chlorophenyl)-N₁-methylbenzene-1,2-diamine

: 1207629-92-2
N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine

Guidance literature:: Multi-step reaction with 3 steps

1.1: bis(dibenzylideneacetone)-palladium⁽⁰⁾; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / Inert atmosphere

2.1: potassium hydride / N,N-dimethyl-formamide / Inert atmosphere

2.2: 80 °C / Inert atmosphere

3.1: copper(l) chloride; potassium borohydride / methanol / Inert atmosphere

With potassium borohydride; potassium hydride; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; copper(l) chloride; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In methanol; N,N-dimethyl-formamide; toluene; 1.1: |Buchwald-Hartwig Coupling;
DOI:10.1021/jo302795w

Reference yield:

: 1207629-87-5
2-chloro-N-methyl-N-(2-nitrophenyl)aniline

: 1207629-92-2
N₁-(2-aminophenyl)-N₂-(2-chlorophenyl)-N₁,N₂-dimethylbenzene-1,2-diamine

Guidance literature:: Multi-step reaction with 4 steps

1.1: copper(l) chloride; potassium borohydride / methanol / Inert atmosphere

2.1: bis(dibenzylideneacetone)-palladium⁽⁰⁾; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene / Inert atmosphere

3.1: potassium hydride / N,N-dimethyl-formamide / Inert atmosphere

3.2: 80 °C / Inert atmosphere

4.1: copper(l) chloride; potassium borohydride / methanol / Inert atmosphere

With potassium borohydride; potassium hydride; caesium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; copper(l) chloride; bis(dibenzylideneacetone)-palladium⁽⁰⁾; In methanol; N,N-dimethyl-formamide; toluene; 2.1: |Buchwald-Hartwig Coupling;
DOI:10.1021/jo302795w