Decahydro-4,8,8-trimethyl-1,4-methanoazulene-9-carbaldehyde

Base Information

• Chemical Name: Decahydro-4,8,8-trimethyl-1,4-methanoazulene-9-carbaldehyde
• CAS No.: 79645-28-6
• Molecular Formula: C15H24 O
• Molecular Weight: 220.355
• European Community (EC) Number: 279-209-6
• DSSTox Substance ID: DTXSID801182423
• Nikkaji Number: J320.130I
• Wikidata: Q67880180
• Mol file: 79645-28-6.mol

Synonyms:Longifolenaldehyde;Decahydro-4,8,8-trimethyl-1,4-methanoazulene-9-carbaldehyde;79645-28-6;EINECS 279-209-6;Longifolenealdehyde;SCHEMBL3001348;DTXSID801182423;Q67880180;Decahydro-4,8,8-trimethyl-1,4-methanoazulene-9-carboxaldehyde

Chemical Property of Decahydro-4,8,8-trimethyl-1,4-methanoazulene-9-carbaldehyde

Chemical Property:

• Boiling Point: 130 °C (0.7 mmHg)
• PSA: 17.07000
• LogP: 3.67390
• XLogP3: 4.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 220.182715385
• Heavy Atom Count: 16
• Complexity: 319

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1(CCCC2(C3C1C(C2C=O)CC3)C)C

Technology Process of Decahydro-4,8,8-trimethyl-1,4-methanoazulene-9-carbaldehyde

There total 6 articles about Decahydro-4,8,8-trimethyl-1,4-methanoazulene-9-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

→ 7β-Formylnorlongifolane (25491-00-3,66537-42-6,79645-28-6)

Guidance literature:

With pyridine; chromium(VI) oxide; for 2h;

Reference yield: 75.0%

isolongifolol (1212326-30-1) → longifolenaldehyde (79645-28-6) + C15H24O (14912-34-6,16755-40-1)

Guidance literature:

With [bis(acetoxy)iodo]benzene; iodine; In cyclohexane; for 8h; Ambient temperature;

Reference yield:

→ Longifolaldehyd (25491-00-3,66537-42-6,79645-28-6)

Guidance literature:

aus Longifolol mit CrO3;

DOI:10.1016/S0040-4020(01)92617-1

upstream raw materials:

isolongifolol

water

longifolan-15-ol

benzene

Downstream raw materials:

α-campholenonitrile

Refernces

• 1、 Satyanarayana, N.,Shitole, H. R.,Nayak, U. R.. "Camphor/Longicamphor and 7β-Formylnorlongifolane/7β-Acetylnorlongifolane Oximes: A Comparative Beckmann Rearrangement Study". . p. 997 - 1001. Retrieved 2007/10/02.