1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene

Base Information

Chemical Name:1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene
CAS No.:914618-49-8
Molecular Formula:C₂₃H₃₅BrO₃
Molecular Weight:439.433
Hs Code.:

Synonyms:1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene

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Chemical Property of 1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene

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Technology Process of 1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene

There total 9 articles about 1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 914618-45-4
1-[2-(2,2-dimethyl-6-methylenecyclohexyl)ethyl]-3-isopropyl-2,4,5-trimethoxybenzene

: 914618-49-8
1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene

Guidance literature:: With bromine; iron(III) chloride; In tetrahydrofuran; at 20 ℃; for 1h;
DOI:10.1002/ejoc.200600361

Reference yield:

: 1193-18-6
3-methylcyclohexen-2-one

: 914618-49-8
1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene

Guidance literature:: Multi-step reaction with 6 steps

1.1: copper(I) bromide / tetrahydrofuran; diethyl ether / 2 h / 0 °C

1.2: 70 percent / DMPU / tetrahydrofuran; diethyl ether / 0 - 20 °C

2.1: zinc; TiCl₄ / tetrahydrofuran / 72 h / 5 °C

2.2: 61 percent / CH₂Cl₂; tetrahydrofuran / 5 °C

3.1: 98 percent / lithium aluminum hydride / tetrahydrofuran / 2 h / 20 °C

4.1: triethylamine / tetrahydrofuran / 1 h / 20 °C

4.2: 95 percent / sodium iodide / tetrahydrofuran / 20 °C

5.1: nBuLi / hexane; heptane / 0.5 h / 20 °C

5.2: 70 percent / tetrahydrofuran; hexane; heptane / 0 °C

6.1: 85 percent / FeCl₃; bromine / tetrahydrofuran / 1 h / 20 °C

With lithium aluminium tetrahydride; n-butyllithium; bromine; iron(III) chloride; titanium tetrachloride; triethylamine; copper(I) bromide; zinc; In tetrahydrofuran; diethyl ether; hexane; n-heptane;
DOI:10.1002/ejoc.200600361

Reference yield:

: 60241-78-3
3-(1-methylethyl)-1,2,4-trimethoxybenzene

: 914618-49-8
1-{2-[2-(bromomethyl)-6,6-dimethylcyclohex-2-en-1-yl]ethyl}-3-isopropyl-2,4,5-trimethoxybenzene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 99 percent / NBS / acetonitrile

2.1: nBuLi / hexane; heptane / 0.5 h / 20 °C

2.2: 70 percent / tetrahydrofuran; hexane; heptane / 0 °C

3.1: 85 percent / FeCl₃; bromine / tetrahydrofuran / 1 h / 20 °C

With N-Bromosuccinimide; n-butyllithium; bromine; iron(III) chloride; In tetrahydrofuran; hexane; n-heptane; acetonitrile;
DOI:10.1002/ejoc.200600361