(S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one

Base Information

Chemical Name:(S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one
CAS No.:1332640-40-0
Molecular Formula:C₂₉H₄₅NO₄
Molecular Weight:471.681
Hs Code.:

Synonyms:(S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one

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Chemical Property of (S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one

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Technology Process of (S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one

There total 14 articles about (S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (2R,3S,4R)-(-)-3,4-O-isopropylidenyl-1-O-triisopropylsilyl-5-hexene-1,2,3,4-tetraol

: 1332640-40-0
(S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one

: C₂₉H₄₅NO₄

Guidance literature:: Multi-step reaction with 4 steps

1: pyridine / 1 h / 0 - 20 °C

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.33 h / 0 - 20 °C

3: sodium hydride / tetrahydrofuran; mineral oil / 4 h / 0 - 20 °C

4: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 24 h / Reflux

With pyridine; tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; dichloromethane; mineral oil;
DOI:10.1039/c4ob01882f

Reference yield:

: (2R,3R,4R)-(-)-3,4-O-isopropylidenyl-2-O-methanesulfonyl-1-O-triisopropylsilyl-5-hexene-1,2,3,4-tetraol

: 1332640-40-0
(S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one

: C₂₉H₄₅NO₄

Guidance literature:: Multi-step reaction with 3 steps

1: tetrabutyl ammonium fluoride / tetrahydrofuran / 0.33 h / 0 - 20 °C

2: sodium hydride / tetrahydrofuran; mineral oil / 4 h / 0 - 20 °C

3: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 24 h / Reflux

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; tetrabutyl ammonium fluoride; sodium hydride; In tetrahydrofuran; dichloromethane; mineral oil;
DOI:10.1039/c4ob01882f

Reference yield:

: (2R,3R,4R)-(-)-3,4-O-isopropylidenyl-2-O-methanesulfonyl-5-hexene-1,2,3,4-tetraol

: 1332640-40-0
(S)-3-benzyl-4-((4S,5R)-2,2-dimethyl-5-((Z)-tetradec-1-enyl)-1,3-dioxolan-4-yl)oxa-zolidin-2-one

: C₂₉H₄₅NO₄

Guidance literature:: Multi-step reaction with 2 steps

1: sodium hydride / tetrahydrofuran; mineral oil / 4 h / 0 - 20 °C

2: tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride / dichloromethane / 24 h / Reflux

With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride; sodium hydride; In tetrahydrofuran; dichloromethane; mineral oil;
DOI:10.1039/c4ob01882f