C₄₂H₆₀O₈Si

Base Information

Chemical Name:C₄₂H₆₀O₈Si
CAS No.:927662-08-6
Molecular Formula:C₄₂H₆₀O₈Si
Molecular Weight:721.019
Hs Code.:

C<sub>42</sub>H<sub>60</sub>O<sub>8</sub>Si

Synonyms:C₄₂H₆₀O₈Si

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Chemical Property of C₄₂H₆₀O₈Si

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Technology Process of C₄₂H₆₀O₈Si

There total 16 articles about C₄₂H₆₀O₈Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: C₄₂H₆₀O₉Si

: 927662-08-6
C₄₂H₆₀O₈Si

Guidance literature:: With triethylsilane; trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -55 ℃; for 0.333333h;
DOI:10.3987/COM-06-S(O)23

Reference yield:

: C₁₀H₁₆O₅

: 927662-08-6
C₄₂H₆₀O₈Si

Guidance literature:: Multi-step reaction with 11 steps

1.1: NaHMDS / tetrahydrofuran; dimethylformamide / 2 h / 20 °C

1.2: p-TSOH*H₂O / methanol; H₂O; tetrahydrofuran / 0.75 h / 20 °C

1.3: 86 percent / 2,6-lutidine / tetrahydrofuran; dimethylformamide / 0.17 h / 0 °C

2.1: 9-BBN / tetrahydrofuran / 3 h / 20 °C / sonication

2.2: H₂O₂; aq. NaHCO₃ / tetrahydrofuran / 1 h / 20 °C

2.3: 99 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.58 h / 20 °C

3.1: 78 percent / Sc(OTf)3 / benzene / 14 h / 20 °C

4.1: Sc(OTf)3 / CH₂Cl₂ / 9.5 h / 20 °C

4.2: 92 percent / K₂CO₃ / methanol / 0.5 h / 20 °C

5.1: 2-nitrobenzeneselenide; Bu₃P / tetrahydrofuran / 0.42 h / 20 °C

5.2: 77 percent / H₂O₂; aq. NaHCO₃ / tetrahydrofuran / 3.5 h / 45 °C

6.1: 89 percent / DIBAL-H / CH₂Cl₂ / 0.5 h / -78 °C

7.1: 76 percent / MeLi / tetrahydrofuran / 1 h / -78 - 20 °C

8.1: 94 percent / Dess-Martin periodinane / CH₂Cl₂ / 1 h / 20 °C

9.1: 9 percent / ruthenium ethylidene complex / toluene / 100 °C

10.1: 45 percent / DDQ / CH₂Cl₂; H₂O / 20 °C

11.1: 83 percent / Et₃SiH; TMSOTf / CH₂Cl₂ / 0.33 h / -55 °C

With triethylsilane; 9-borabicyclo[3.3.1]nonane dimer; tributylphosphine; trimethylsilyl trifluoromethanesulfonate; methyllithium; sodium hexamethyldisilazane; diisobutylaluminium hydride; Dess-Martin periodane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; scandium tris(trifluoromethanesulfonate); ruthenium ethylidene complex; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.3987/COM-06-S(O)23

Reference yield:

: 927661-96-9
C₂₇H₃₈O₄Si

: 927662-08-6
C₄₂H₆₀O₈Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: 9-BBN / tetrahydrofuran / 3 h / 20 °C / sonication

1.2: H₂O₂; aq. NaHCO₃ / tetrahydrofuran / 1 h / 20 °C

1.3: 99 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.58 h / 20 °C

2.1: 78 percent / Sc(OTf)3 / benzene / 14 h / 20 °C

3.1: Sc(OTf)3 / CH₂Cl₂ / 9.5 h / 20 °C

3.2: 92 percent / K₂CO₃ / methanol / 0.5 h / 20 °C

4.1: 2-nitrobenzeneselenide; Bu₃P / tetrahydrofuran / 0.42 h / 20 °C

4.2: 77 percent / H₂O₂; aq. NaHCO₃ / tetrahydrofuran / 3.5 h / 45 °C

5.1: 89 percent / DIBAL-H / CH₂Cl₂ / 0.5 h / -78 °C

6.1: 76 percent / MeLi / tetrahydrofuran / 1 h / -78 - 20 °C

7.1: 94 percent / Dess-Martin periodinane / CH₂Cl₂ / 1 h / 20 °C

8.1: 9 percent / ruthenium ethylidene complex / toluene / 100 °C

9.1: 45 percent / DDQ / CH₂Cl₂; H₂O / 20 °C

10.1: 83 percent / Et₃SiH; TMSOTf / CH₂Cl₂ / 0.33 h / -55 °C

With triethylsilane; 9-borabicyclo[3.3.1]nonane dimer; tributylphosphine; trimethylsilyl trifluoromethanesulfonate; methyllithium; diisobutylaluminium hydride; Dess-Martin periodane; 2,3-dicyano-5,6-dichloro-p-benzoquinone; scandium tris(trifluoromethanesulfonate); ruthenium ethylidene complex; In tetrahydrofuran; dichloromethane; water; toluene; benzene;
DOI:10.3987/COM-06-S(O)23