P,P-Bis(3-methoxyphenyl)phosphinous chloride

Base Information

Chemical Name:P,P-Bis(3-methoxyphenyl)phosphinous chloride
CAS No.:13685-31-9
Molecular Formula:C₁₄H₁₄ClO₂P
Molecular Weight:280.691
Hs Code.:
DSSTox Substance ID:DTXSID301258134

Synonyms:P,P-Bis(3-methoxyphenyl)phosphinous chloride;SCHEMBL2154398;DTXSID301258134;13685-31-9

Suppliers and Price of P,P-Bis(3-methoxyphenyl)phosphinous chloride

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of P,P-Bis(3-methoxyphenyl)phosphinous chloride

Chemical Property:

XLogP3:3.8
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:4
Exact Mass:280.0419944
Heavy Atom Count:18
Complexity:228

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:COC1=CC(=CC=C1)P(C2=CC=CC(=C2)OC)Cl

Technology Process of P,P-Bis(3-methoxyphenyl)phosphinous chloride

There total 2 articles about P,P-Bis(3-methoxyphenyl)phosphinous chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 71360-01-5
ortho-methoxydiphenylphosphine oxide

: 13685-31-9
chlorobis(3-methoxyphenyl)phosphine

Guidance literature:: With phosphorus trichloride; In benzene; at 0 ℃; Inert atmosphere; Glovebox; Heating;
DOI:10.1002/anie.202106871

Reference yield:

: 2398-37-0
3-methoxyphenyl bromide

: 13685-31-9
chlorobis(3-methoxyphenyl)phosphine

Guidance literature:: 3-methoxyphenyl bromide; With magnesium; In tetrahydrofuran; for 2h; Reflux;

With phosphorus trichloride; In tetrahydrofuran; at 20 ℃;
DOI:10.1016/j.tetasy.2010.05.031

Reference yield: 34.0%

: (S)-N,N-dimethyl-1-ferrocenylethylamine

: 13685-31-9
chlorobis(3-methoxyphenyl)phosphine

: (S)-N,N-dimethyl-1-[(R)-2-[bis(3-methoxyphenyl)phosphino]ferrocenyl]ethylamine

Guidance literature:: With n-butyllithium; In diethyl ether; hexane; addition of BuLi in ether to complex in ether at 25-27°C over 20min, stirred at room temperature for 1.5 h, addition of phosphine in ether to a refluxed mixture over 45 min, refluxed for 4 h, N2 atm.; addition of aq. NaHCO3, washing of organic layer with water, drying with NaSO4, evapn. in vac., chromy. (alumina, hexane/benzene 3/1), recrystn. (hexane); elem. anal.;
DOI:10.1246/bcsj.53.1138