2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester

Base Information

Chemical Name:2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester
CAS No.:1262225-35-3
Molecular Formula:C₁₉H₂₂BO₄P
Molecular Weight:356.166
Hs Code.:

Synonyms:2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester

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Chemical Property of 2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester

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Technology Process of 2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester

There total 3 articles about 2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 127686-75-3
allyl(diphenyl)phosphine-borane

: 79-22-1
methyl chloroformate

: 1262225-35-3
2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester

Guidance literature:: allyl(diphenyl)phosphine-borane; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.5h; Inert atmosphere;

methyl chloroformate; In tetrahydrofuran; hexane; at -78 - 20 ℃; regioselective reaction; Inert atmosphere;
DOI:10.3998/ark.5550190.0012.511

Reference yield:

: 41593-58-2
diphenylphosphineborane

: 1262225-35-3
2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2.2: -78 - 20 °C / Inert atmosphere

With n-butyllithium; In tetrahydrofuran; hexane;
DOI:10.3998/ark.5550190.0012.511

Reference yield:

: 603-35-0
triphenylphosphine

: 1262225-35-3
2-(diphenylboranatophosphinyl)pent-2-eno-1,5-dicarboxylic acid dimethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: borane-THF / tetrahydrofuran / 1 h / Inert atmosphere

2.1: sodium; ammonium chloride / tetrahydrofuran / 24 h / 20 °C / Inert atmosphere

3.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere

3.2: Inert atmosphere

4.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

4.2: -78 - 20 °C / Inert atmosphere

With n-butyllithium; borane-THF; sodium; ammonium chloride; In tetrahydrofuran; hexane;
DOI:10.3998/ark.5550190.0012.511