[2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate

Base Information

Chemical Name:[2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate
CAS No.:1439562-00-1
Molecular Formula:C₂₆H₂₇NO₃S
Molecular Weight:433.571
Hs Code.:

Synonyms:[2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate

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Chemical Property of [2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate

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Technology Process of [2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate

There total 10 articles about [2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

: 13889-93-5
S-isopropyl chlorothiocarbonate

: rac-2-(2,6-dimethyl-4-prop-1-ynylphenyl)-4-(pyridin-2-ylmethyl)cyclopentane-1,3-dione

: 1439562-00-1
[2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate

Guidance literature:: rac-2-(2,6-dimethyl-4-prop-1-ynylphenyl)-4-(pyridin-2-ylmethyl)cyclopentane-1,3-dione; With N-ethyl-N,N-diisopropylamine; In dichloromethane; for 0.5h; Cooling;

S-isopropyl chlorothiocarbonate; In dichloromethane; at 20 ℃;

Reference yield: 18.0%

: 13889-93-5
S-isopropyl chlorothiocarbonate

: C₂₂H₂₁NO₂

: 1439562-00-1
[2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate

Guidance literature:: C₂₂H₂₁NO₂; With N-ethyl-N,N-diisopropylamine; In dichloromethane; for 0.5h; Cooling;

S-isopropyl chlorothiocarbonate; In dichloromethane; at 20 ℃;

Reference yield:

: 2-(4-bromo-2,6-dimethylphenyl)-5-(hydroxypyridin-2-ylmethyl)-3-methoxycyclopent-2-enone

: 1439562-00-1
[2-(2,6-dimethyl-4-prop-1-ynyl-phenyl)-3-oxo-4-(2-pyridylmethyl)cyclopenten-1-yl] isopropylsulfanylformate

Guidance literature:: Multi-step reaction with 6 steps

1.1: triethylamine / dichloromethane / 0 - 20 °C

2.1: potassium carbonate / methanol / 25 - 30 °C

3.1: acetic acid; zinc / 25 - 30 °C

4.1: bis-triphenylphosphine-palladium(II) chloride; 1,4-di(diphenylphosphino)-butane; tetrabutyl ammonium fluoride / tetrahydrofuran; dimethyl sulfoxide / 0.67 h / 110 °C / Inert atmosphere

5.1: hydrogenchloride / acetone; water / 0.67 h / 80 °C / Microwave irradiation

6.1: N-ethyl-N,N-diisopropylamine / dichloromethane / 0.5 h / Cooling

6.2: 20 °C

With hydrogenchloride; bis-triphenylphosphine-palladium(II) chloride; tetrabutyl ammonium fluoride; potassium carbonate; acetic acid; triethylamine; N-ethyl-N,N-diisopropylamine; 1,4-di(diphenylphosphino)-butane; zinc; In tetrahydrofuran; methanol; dichloromethane; water; dimethyl sulfoxide; acetone;