(1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol

Base Information

• Chemical Name: (1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol
• CAS No.: 1114568-38-5
• Molecular Formula: C₁₆H₂₂OSe
• Molecular Weight: 309.31
• Mol file: 1114568-38-5.mol

Synonyms:(1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol

Chemical Property of (1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol

There total 4 articles about (1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

diphenyl diselenide (1666-13-3) + (1S,3R,4S,6R)-3,4-epoxy-3,7,7-trimethylbicyclo[4.1.0]heptane (936-92-5) → (1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol (1114568-38-5)

Guidance literature:

With sodium tetrahydroborate; In methanol; for 3h; Reflux;

DOI:10.1080/10426500902947682

Reference yield: 59.0%

diphenyl diselenide (1666-13-3) + 3β,4β-Carandiol-monotosylat (33116-78-8,39815-45-7,52153-56-7,57129-21-2,77448-79-4) → (1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol (1114568-38-5)

Guidance literature:

With sodium tetrahydroborate; In methanol; at 50 ℃; for 24h; Inert atmosphere;

DOI:10.1002/ejoc.201500211

Reference yield: 55.0%

N-phenylselenenyl succinimide (68395-72-2) + (+)-Δ3-carene (498-15-7,19079-29-9) → (1S,3R,4R,6R)-3,7,7-trimethyl-4-(phenylselenyl)bicyclo[4.1.0]heptan-3-ol (1114568-38-5)

Guidance literature:

With camphor-10-sulfonic acid; water; In dichloromethane; at 20 ℃; for 24h; Inert atmosphere;

DOI:10.1080/10426500902947682

upstream raw materials:

(+)-Δ³-carene

phenylselenyl triflate

N-phenylselenenyl succinimide

diphenyl diselenide