(E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol

Base Information

Chemical Name:(E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol
CAS No.:1449224-49-0
Molecular Formula:C₁₆H₂₂O₂
Molecular Weight:246.349
Hs Code.:

Synonyms:(E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol

Suppliers and Price of (E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol

Chemical Property:

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Technology Process of (E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol

There total 4 articles about (E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: C₁₆H₂₀O₂

: 1449224-49-0
(E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol

Guidance literature:: With diisobutylaluminium hydride; In dichloromethane; at -78 ℃; Inert atmosphere;
DOI:10.1002/anie.201208132

Reference yield:

: C₁₃H₁₆O

: 1449224-49-0
(E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydride / tetrahydrofuran / 0 °C / Inert atmosphere

2: disodium ethylenediaminetetraacetic acid; potassium carbonate; Oxone; borax; tetra(n-butyl)ammonium hydrogensulfate / water; acetonitrile / 0 °C / Inert atmosphere

3: diisobutylaluminium hydride / dichloromethane / -78 °C / Inert atmosphere

With borax; Oxone; tetra(n-butyl)ammonium hydrogensulfate; disodium ethylenediaminetetraacetic acid; sodium hydride; diisobutylaluminium hydride; potassium carbonate; In tetrahydrofuran; dichloromethane; water; acetonitrile;
DOI:10.1002/anie.201208132

Reference yield:

: 928-90-5
5-hexyl-1-ol

: 1449224-49-0
(E)-7-((2R,3R)-3-benzyloxiran-2-yl)hept-3-en-2-ol

Guidance literature:: Multi-step reaction with 6 steps

1.1: diisobutylaluminium hydride / hexane / -78 °C / Inert atmosphere

1.2: Inert atmosphere

2.1: palladium bis[bis(diphenylphosphino)ferrocene] dichloride / tetrahydrofuran / Inert atmosphere

3.1: silica gel; pyridinium chlorochromate / dichloromethane

4.1: sodium hydride / tetrahydrofuran / 0 °C / Inert atmosphere

5.1: disodium ethylenediaminetetraacetic acid; potassium carbonate; Oxone; borax; tetra(n-butyl)ammonium hydrogensulfate / water; acetonitrile / 0 °C / Inert atmosphere

6.1: diisobutylaluminium hydride / dichloromethane / -78 °C / Inert atmosphere

With borax; Oxone; palladium bis[bis(diphenylphosphino)ferrocene] dichloride; tetra(n-butyl)ammonium hydrogensulfate; silica gel; disodium ethylenediaminetetraacetic acid; sodium hydride; diisobutylaluminium hydride; potassium carbonate; pyridinium chlorochromate; In tetrahydrofuran; hexane; dichloromethane; water; acetonitrile;
DOI:10.1002/anie.201208132