methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone

Base Information

Chemical Name:methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone
CAS No.:113668-65-8
Molecular Formula:C₂₃H₂₆N₂O₈S
Molecular Weight:490.534
Hs Code.:

Synonyms:methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone

Suppliers and Price of methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone

There total 3 articles about methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 111476-69-8
methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexopyranosid-3-ulose

: 1576-35-8
toluene-4-sulfonic acid hydrazide

: 113668-65-8
methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone

Guidance literature:: In ethanol; for 0.5h; Ambient temperature;
DOI:10.1021/jo00244a050

Reference yield: 91.0%

: 113668-66-9
methyl 4-O-acetyl-2-O-benzoyl-3,6-dideoxy-3-<2-(p-tolylsulfonyl)hydrazino>-α-L-altro-hexopyranoside

: 113668-65-8
methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone

Guidance literature:: With 4-methyl-morpholine; N-iodo-succinimide; In chloroform; at 0 ℃;
DOI:10.1021/jo00283a047

Reference yield:

: 79681-50-8
methyl 4-O-acetyl-2-O-benzoyl-α-L-rhamnopyranoside

: 113668-65-8
methyl 4-O-acetyl-2-O-benzoyl-6-deoxy-α-L-arabinohexapyranosid-3-ulose (p-tolylsulfonyl)hydrazone

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / pyridinium chlorochromate, molecular sieves / CH₂Cl₂ / 1.) from -78 deg C to RT, 2.) RT, 2 h

2: 100 percent / ethanol / 0.5 h / Ambient temperature

With molecular sieve; pyridinium chlorochromate; In ethanol; dichloromethane;
DOI:10.1021/jo00244a050